1027042-05-2

Upstream product

• 612846-87-4 [(2R,4S,5S,6R)-6-(5,5-Dimethyl-[1,3]dioxan-2-ylmethyl)-4-(4-methoxy-benzyloxy)-5-methyl-5-triisopropylsilanyloxymethyl-tetrahydro-pyran-2-yl]-methanol 
• 532-32-1 sodium benzoate 
• 612846-83-0 ((2S,4R,5R)-4-Allyl-5-methyl-2-phenyl-[1,3]dioxan-5-yl)-methanol 
• 612846-86-3 Benzoic acid (2R,4S,5S,6R)-6-allyl-4-(4-methoxy-benzyloxy)-5-methyl-5-triisopropylsilanyloxymethyl-tetrahydro-pyran-2-ylmethyl ester 
• 612846-81-8 (4R,5R,6S)-6-(4-Methoxy-benzyloxy)-5-methyl-5-triisopropylsilanyloxymethyl-nona-1,8-dien-4-ol 
• 612846-85-2 (1S)-1-[(2S,4R,5S)-4-allyl-5-methyl-2-phenyl-1,3-dioxan-5-yl]but-3-en-1-ol 
• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 13154-24-0 triisopropylsilyl chloride 

Downstream Products

• 612846-89-6 (E)-4-[(2R,4S,5S,6R)-6-(5,5-Dimethyl-[1,3]dioxan-2-ylmethyl)-4-(4-methoxy-benzyloxy)-5-methyl-5-triisopropylsilanyloxymethyl-tetrahydro-pyran-2-yl]-but-3-en-1-ol 

Relevant academic research and scientific papers

A stereoselective synthesis of the C15-C25 subunit of (+)-lasonolide A

The C15-C25 upper THP segment 2 of (+)-lasonolide A has been synthesized efficiently via diastereomeric differentiation, iodocyclization and Julia-Kocieński's sulfone olefination to install its quaternary chiral center, cis-2,6-disubstituted THP and trans-olefin, respectively.