102779-23-7

Downstream Products

• 102779-27-1 [Pt(C₆F₅)2(C₅H₅N)(CO)] 
• 102725-44-0 [P(C₆H₅)2(CH₃)2]⁽¹⁺⁾*[Pt(C₆F₅)2I(CO)]^(1-)=[P(C₆H₅)2(CH₃)2][Pt(C₆F₅)2I(CO)] 
• 102779-29-3 [P(C₆H₅)3C₂H₅]⁽¹⁺⁾*[Pt(C₆F₅)2Br(CO)]^(1-)=[P(C₆H₅)3C₂H₅][Pt(C₆F₅)2Br(CO)] 
• 102779-25-9 [N(P(C₆H₅)3)2]⁽¹⁺⁾*[Pt(C₆F₅)2Cl(CO)]^(1-)=[N(P(C₆H₅)3)2][Pt(C₆F₅)2Cl(CO)] 
• 102725-36-0 [Pt(C₆F₅)2(C₅H₅N)(CO)] 
• 102725-40-6 [P(C₆H₅)3C₂H₅]⁽¹⁺⁾*[Pt(C₆F₅)2Br(CO)]^(1-)=[P(C₆H₅)3C₂H₅][Pt(C₆F₅)2Br(CO)] 

Relevant academic research and scientific papers

Synthesis and reactivity of cis and trans dicarbonyl derivatives of platinum(II)

Direct carbonylation of cis-[Pt(C6X5)2(OC4H 8)2] (X = F (1), Cl (2)) with CO (room temperature, PCO ≈ 1 atm) gives cis-[Pt(C6X5)2(CO)2] (X = F (3), Cl (4)) as white, stable solids. The synthesis of trans-[Pt(C6F5)2(CO)2] (5) by carbonylation of (NBu4) [trans-Pt(C6F5)2Cl(CO)] in the presence of AgClO4 is also described. Addition of neutral or anionic ligands to dichloromethane solutions of 3, 4, or 5 results in substitution of one CO group and affords cis- or trans-[Pt(C6X5)2L(CO)]n- (n = 0, 1).