Synthesis and reactivity of cis and trans dicarbonyl derivatives of platinum(II)

DOI: 10.1021/om00139a012

Source and publish data:

Organometallics p. 1581 - 1584 (1986)

Update date:2022-08-03

Topics:

Authors:

Usón, Rafael

Forniés, Juan

Tomás, Milagros

Menjón, Babil

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Article abstract of DOI:10.1021/om00139a012

Direct carbonylation of cis-[Pt(C₆X₅)₂(OC₄H ₈)₂] (X = F (1), Cl (2)) with CO (room temperature, P_CO ≈ 1 atm) gives cis-[Pt(C₆X₅)₂(CO)₂] (X = F (3), Cl (4)) as white, stable solids. The synthesis of trans-[Pt(C₆F₅)₂(CO)₂] (5) by carbonylation of (NBu₄) [trans-Pt(C₆F₅)₂Cl(CO)] in the presence of AgClO₄ is also described. Addition of neutral or anionic ligands to dichloromethane solutions of 3, 4, or 5 results in substitution of one CO group and affords cis- or trans-[Pt(C₆X₅)₂L(CO)]^n- (n = 0, 1).

Full text of DOI:10.1021/om00139a012

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