Organometallics p. 1581 - 1584 (1986)
Update date:2022-08-03
Topics:
Usón, Rafael
Forniés, Juan
Tomás, Milagros
Menjón, Babil
Direct carbonylation of cis-[Pt(C6X5)2(OC4H 8)2] (X = F (1), Cl (2)) with CO (room temperature, PCO ≈ 1 atm) gives cis-[Pt(C6X5)2(CO)2] (X = F (3), Cl (4)) as white, stable solids. The synthesis of trans-[Pt(C6F5)2(CO)2] (5) by carbonylation of (NBu4) [trans-Pt(C6F5)2Cl(CO)] in the presence of AgClO4 is also described. Addition of neutral or anionic ligands to dichloromethane solutions of 3, 4, or 5 results in substitution of one CO group and affords cis- or trans-[Pt(C6X5)2L(CO)]n- (n = 0, 1).
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