102877-65-6Relevant articles and documents
N-Methyl-N-(2-nitrophenyl)nitramine and N-methyl-N-(3-nitrophenyl)- nitramine
Zarychta, Bartosz,Piecyk-Mizgala, Anna,Daszkiewicz, Zdzislaw,Zaleski, Jacek
, p. o515-o517 (2005)
The structures of the two title isomeric compounds (systematic names: N-methyl-N,2-dinitroaniline and N-methyl-N,3-dinitroaniline, both C 7H7N3O4) are slightly different because they exhibit different steric hindrances and hydrogen-bonding environments. The aromatic rings are planar. The -N(Me)NO2 and -NO2 groups are not coplanar with the rings. Comparison of the geometric parameters of the ortho, meta and para isomers together with those of N-methyl-N-phenylnitramine suggests that the position of the nitro group has a strong influence on the aromatic ring distortion. The crystal packing is stabilized by weak C-H...O hydrogen bonds to the nitramine group.
Synthesis and properties of secondary N-nitroamines
Prezhdo,Daszkiewicz,Kyziol,Bykova,Prezhdo
, p. 410 - 416 (2007/10/03)
Secondary arylamines and related compounds can readily be converted into the corresponding N-nitroamines by treatment of their organomagnesium derivatives with butyl nitrate. The yield of the products ranges from 45 to 77%. Secondary aromatic N-nitroamine
