102913-61-1Relevant articles and documents
Keto-Enol Thermodynamics of Breslow Intermediates
Paul, Mathias,Breugst, Martin,Neud?rfl, J?rg-Martin,Sunoj, Raghavan B.,Berkessel, Albrecht
, p. 5044 - 5051 (2016)
Breslow intermediates, first postulated in 1958, are pivotal intermediates in carbene-catalyzed umpolung. Attempts to isolate and characterize these fleeting amino enol species first met with success in 2012 when we found that saturated bis-Dipp/Mes imida