102920-75-2Relevant academic research and scientific papers
Element-Organic Amine/Imine Compounds, XXVII: Palladium and Platinum Complexes with Diamidochalkogenophosphoric Acid Derivatives as Ligands
Scherer, Otto J.,Forstinger, Klaus,Kaub, Juergen,Sheldrick, William S.
, p. 2731 - 2747 (2007/10/02)
RR'NP(X)=NR (1), R = tBu, R'= SiMe3; X = S, Se, adds water with formation of (RHN)2P(X)OR'(2). 2 and NaOH afford the salts Na (3). (Ph3P)2MO2 and 2 as well as (Ph3P)2MCl2 (M = Pd, Pt) and 3 react with formation of cis-2> (4) and (5).The interaction of 3 with trans- (6) gives the multinuclear palladium complexes (PdL2)n, L = SP(O)(NHR)2, 7 (n = 3), 8 (n = 2). 5 (M = Pt, X = S, Se) and 7 have been characterized additionally by an X-ray structure analysis.
