1029693-91-1Relevant academic research and scientific papers
Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)
Neo, Kian Eang,Huynh, Han Vinh,Koh, Lip Lin,Henderson, William,Hor, T.S. Andy
, p. 1628 - 1635 (2008)
Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid.
