760996-75-6

Basic information

• Product Name: [PdCl(CH(CH₂CH₂PPh₂)2)]
• CAS NO: 760996-75-6
• Molecular Weight: 581.37
• Mol File: 760996-75-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [PdCl(CH(CH₂CH₂PPh₂)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [PdCl(CH(CH₂CH₂PPh₂)2)](760996-75-6)
• EPA Substance Registry System: [PdCl(CH(CH₂CH₂PPh₂)2)](760996-75-6)

Safety Data

• Hazardous Substances Data: 760996-75-6(Hazardous Substances Data)

Upstream product

• 27721-02-4 1,5-bis-(diphenylphosphino)pentane 
• 7647-14-5 sodium chloride 
• 60975-62-4 {(1,5-bis(diphenyphosphino)pentane)PdCl₂} 

Downstream Products

• 1029693-91-1 [Pd2(μ-Cl)(CH(CH2CH2PPh2)2)2]BF4 
• 138764-82-6 [Ag(4-pyS)]_n 
• 1029693-88-6 [Pd(nitrate)(CH(CH₂CH₂PPh₂)2)] 

Relevant articles and documents

Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)

Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid.