103110-98-1

Basic information

• Product Name: N-methyl-2,6-di(isopropyl)aniline
• Synonyms: N-methyl-2,6-di(isopropyl)aniline
• CAS NO: 103110-98-1
• Molecular Weight: 191.316
• Mol File: 103110-98-1.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: N-methyl-2,6-di(isopropyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-2,6-di(isopropyl)aniline(103110-98-1)
• EPA Substance Registry System: N-methyl-2,6-di(isopropyl)aniline(103110-98-1)

Safety Data

• Hazardous Substances Data: 103110-98-1(Hazardous Substances Data)

Upstream product

• 60090-48-4 2,6-di(isopropyl)-N-methyleneaniline 
• 24544-04-5 2,6-diisopropylbenzenamine 
• 64-18-6 formic acid 
• 124-38-9 carbon dioxide 
• 84250-69-1 N-(2,6-diisopropylphenyl)formamide 
• 74-88-4 methyl iodide 

Downstream Products

• 142039-16-5 bis{(2,6-diisopropylphenyl)methylamino}borane 
• 142039-18-7 bis({(2,6-diisopropylphenyl)methylamino}methoxyboryl)oxide 
• 142039-19-8 bis{(2,6-diisopropylphenyl)methylamino}fluoroborane 
• 2909-77-5 N,N-dimethyl-2,6-di(isopropyl)aniline 
• 35340-18-2 N-Methyl-2,6-diisopropyl-formanilid 
• 142039-14-3 {(2,6-diisopropylphenyl)methylamino}difluoroborane 
• 191799-01-6 3-Methoxy-pyridine-2-carboxylic acid tert-butyl-cyclohexyl-amide 
• 1320352-83-7 2,6-diisopropyl-N-methyl-4-thiocyanatoaniline 
• 1320352-84-8 4-bromo-2,6-diisopropyl-N-methylaniline 

Relevant articles and documents

Observation of a Stable Monomeric N-Methylene Aromatic Amine

The first free N-methyleneaniline stable under ordinary conditions was authenticated by spectroscopic and analytical data and some of its reactions were observed; a room temperature equilibrium between another free N-methylene aromatic amine and its oligomeric species is reported.

N-heterocyclic carbene copper(i) catalysed N-methylation of amines using CO2

The N-methylation of amines using CO2 and PhSiH3 as source of CH3 was efficiently performed using a N-heterocyclic carbene copper(i) complex. The methodology was found compatible with aromatic and aliphatic primary and secondary amines. Synthetic and computational studies have been carried out to support the proposed reaction mechanism for this transformation.

CO2 as a C1-building block for the catalytic methylation of amines

A novel catalytic reaction has been designed to utilize, for the first time, CO2 as a C1 feedstock in the synthesis of N-methylamines. Simple zinc catalysts, based on commercially available zinc salts and ligands, prove highly efficient in promoting both a 6 electron reduction of carbon dioxide and the formation of a C-N bond, using hydrosilanes and amines.