103136-42-1

Upstream product

• 4753-07-5 2,3,6,2',3',4',6'-hepta-O-acetyl-lactosyl bromide 
• 52211-61-7 (2S,3R,4S,5R,6R)-2-(((2R,3S,4R,5R,6R)-6-(allyloxy)-4,5-dihydroxy-2-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol 
• 50256-34-3 allyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-2,3,6-tri-O-acetyl-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 103136-40-9 Allyl O-(3,4-O-isopropylidene-β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside 

Downstream Products

• 148979-88-8 Allyl O-(2,3,6-tri-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 115920-06-4 C₆₉H₇₉NO₂₃ 
• 115920-06-4 C₆₉H₇₉NO₂₃ 
• 109681-28-9 allyl 2,3,6-tri-O-benzyl-4-O-<2,6-di-O-benzyl-3-O-(methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-α-D-erythro-L-gluco-2-nonulopyranosylate)-β-D-galactopyranosyl>-β-D-glucopyranoside 
• 109681-29-0 allyl 2,3,6-tri-O-benzyl-4-O-<2,6-di-O-benzyl-3-O-(methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-β-D-erythro-L-gluco-2-nonulopyranosylate)-β-D-galactopyranosyl>-β-D-glucopyranoside 
• 103136-44-3 Allyl O-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

AN EFFECTIVE SYNTHESIS OF α-GLYCOSIDES OF N-ACETYLNEURAMINIC ACID DERIVATIVES BY USE OF 2-DEOXY-2β-HALO-3β-HYDROXY-4,7,8,9-TETRA-O-ACETYL-N-ACETYLNEURAMINIC ACID METHYL ESTER

Condensation of the acetyl protected 2-deoxy-2β-halo-3β-hydroxy-N-acetylneuraminic acid methyl ester with various acceptors such as properly protected glucose, galactose, and lactose derivatives in the presence of silver triflate gave the NeuAc α-glycosid

AN EFFECTIVE SYNTHESIS OF α-GLYCOSIDES OF N-ACETYLNEURAMINIC ACID BY USE OF 2β-HALO-3β-HYDROXY-4,7,8,9-TETRA-O-ACETYL-N-ACETYLNEURAMINIC ACID METHYL ESTER

Glycosylations of 2β-chloro- and 2β-bromo-3β-hydroxy-N-acetylneuraminic acid derivatives with various acceptors such as 6-unprotected glucose, 3-unprotected galactose, and 3'-unprotected lactose derivatives (1.0 equiv) were carried out in the presence of