103136-44-3

Upstream product

• 103136-42-1 allyl 2,3,6-tri-O-benzyl-6-O-(2,6-di-O-benzyl-3,4-O-isopropylidene-β-D-galactopyranosyl)-β-D-glucopyranoside 
• 4753-07-5 2,3,6,2',3',4',6'-hepta-O-acetyl-lactosyl bromide 
• 100-39-0 benzyl bromide 
• 52211-61-7 (2S,3R,4S,5R,6R)-2-(((2R,3S,4R,5R,6R)-6-(allyloxy)-4,5-dihydroxy-2-(hydroxymethyl)tetrahydro-2H-pyran-3-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol 
• 50256-34-3 allyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-2,3,6-tri-O-acetyl-β-D-glucopyranoside 
• 103136-40-9 Allyl O-(3,4-O-isopropylidene-β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside 

Downstream Products

• 148979-88-8 Allyl O-(2,3,6-tri-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 137896-88-9 allyl O-(2,6-di-O-benzyl-3,4-isopropylidene-α-D-galactopyranosyl)-(1->4)-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 137896-87-8 allyl O-(2,6-di-O-benzyl-3,4-isopropylidene-β-D-galactopyranosyl)-(1->3)-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 137896-86-7 allyl O-(2,6-di-O-benzyl-3,4-isopropylidene-α-D-galactopyranosyl)-(1->3)-(2,6-di-O-benzyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 115920-06-4 C₆₉H₇₉NO₂₃ 
• 115920-06-4 C₆₉H₇₉NO₂₃ 
• 109681-29-0 allyl 2,3,6-tri-O-benzyl-4-O-<2,6-di-O-benzyl-3-O-(methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-β-D-erythro-L-gluco-2-nonulopyranosylate)-β-D-galactopyranosyl>-β-D-glucopyranoside 
• 109681-28-9 allyl 2,3,6-tri-O-benzyl-4-O-<2,6-di-O-benzyl-3-O-(methyl 5-acetamido-4,7,8,9-tetra-O-acetyl-5-deoxy-α-D-erythro-L-gluco-2-nonulopyranosylate)-β-D-galactopyranosyl>-β-D-glucopyranoside 

Relevant academic research and scientific papers

A novel approach to functionalization of allyl aglycon. Effective synthesis of selectively protected 2-aminoethyl lactoside, a common building block for the synthesis of carbohydrate chains of glycolipids

A novel approach to the funclionalizaiion of aglycon in allyl glycosides is described. The method comprises ozonolysis of the double bond in the allyl group, leading to the corresponding aldehyde, and subsequent transformation of the latter into the corre

AN EFFECTIVE SYNTHESIS OF α-GLYCOSIDES OF N-ACETYLNEURAMINIC ACID DERIVATIVES BY USE OF 2-DEOXY-2β-HALO-3β-HYDROXY-4,7,8,9-TETRA-O-ACETYL-N-ACETYLNEURAMINIC ACID METHYL ESTER

Condensation of the acetyl protected 2-deoxy-2β-halo-3β-hydroxy-N-acetylneuraminic acid methyl ester with various acceptors such as properly protected glucose, galactose, and lactose derivatives in the presence of silver triflate gave the NeuAc α-glycosid

AN EFFECTIVE SYNTHESIS OF α-GLYCOSIDES OF N-ACETYLNEURAMINIC ACID BY USE OF 2β-HALO-3β-HYDROXY-4,7,8,9-TETRA-O-ACETYL-N-ACETYLNEURAMINIC ACID METHYL ESTER

Glycosylations of 2β-chloro- and 2β-bromo-3β-hydroxy-N-acetylneuraminic acid derivatives with various acceptors such as 6-unprotected glucose, 3-unprotected galactose, and 3'-unprotected lactose derivatives (1.0 equiv) were carried out in the presence of