103150-22-7

Basic information

• Product Name: exo-1-methoxy-7-phenyl-cis-bicyclo<4.2.0>octan-8-one
• Synonyms: exo-1-methoxy-7-phenyl-cis-bicyclo<4.2.0>octan-8-one
• CAS NO: 103150-22-7
• Molecular Weight: 230.307
• Mol File: 103150-22-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: exo-1-methoxy-7-phenyl-cis-bicyclo<4.2.0>octan-8-one(CAS DataBase Reference)
• NIST Chemistry Reference: exo-1-methoxy-7-phenyl-cis-bicyclo<4.2.0>octan-8-one(103150-22-7)
• EPA Substance Registry System: exo-1-methoxy-7-phenyl-cis-bicyclo<4.2.0>octan-8-one(103150-22-7)

Safety Data

• Hazardous Substances Data: 103150-22-7(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 
• 103150-19-2 exo-7-chloro-endo-7-phenyl-cis-bicyclo<4.2.0>octan-8-one 
• 2912-62-1 α-chlorophenylacetyl chloride 
• 124-41-4 sodium methylate 
• 103150-26-1 exo-1-<(2,4,6-trimethylbenzoyl)oxy>-7-phenyl-cis-bicyclo<4.2.0>octan-8-one 
• 103150-24-9 exo-1-<(o-methoxybenzoyl)oxy>-7-phenyl-cis-bicyclo<4.2.0>octan-8-one 
• 103150-25-0 exo-1-(phenylacetoxy)-7-phenyl-cis-bicyclo<4.2.0>octan-8-one 
• 103150-23-8 exo-1-(benzyloxy)-7-phenyl-cis-bicyclo<4.2.0>octan-8-one 
• 103150-21-6 exo-1-acetoxy-7-phenyl-cis-bicyclo<4.2.0>octan-8-one 

Relevant articles and documents

Allylic Displacements and a Novel Ester-Ether Interchange in Fused Cyclobutanones

Chlorophenylcyclobutanone 11, prepared by chlorophenylketene addition to cyclohexene, reacts readily with simple and hindered carboxylic acids in a cine substitution to produce keto esters 14.The acyloxy and phenyl substituents in 14c are shown by X-ray diffraction to be cis oriented; nevertheless 14 reacts with NaOMe at 20 deg C by an unusual ester-ether interchange to produce 15 and the released carboxylate RCO2-.These reactions apparently proceed via an oxyallyl cation intermediate.The behaviors of related cyclobutanones 4, 6, and 11 with methoxide are contrasted.