103262-97-1Relevant academic research and scientific papers
PALLADIUM CATALYZED INDIRECT ELECTROCHEMICAL ACETOXYLATION OF OLEFINS
Hartstock, Frederick W.,Wayner, Danial, D. M.
, p. 8137 - 8140 (1994)
Olefins are acetoxylated to allylic and vinylic unsaturated esters by palladium (II) acetate catalyst in combination with controlled current anodic reoxidation and copper (II) acetate as an electron transfer agent.
Highly enantioselective Rh-catalysed hydrogenation of 1-alkyl vinyl esters using phosphine-phosphoramidite ligands
Konrad, Tina Maria,Schmitz, Pascal,Leitner, Walter,Francio, Giancarlo
supporting information, p. 13299 - 13303 (2013/10/08)
MatPhos, a good mate for hard tasks: The asymmetric hydrogenation of 1-alkyl vinyl esters, thwarted so far by mediocre ee values and low activities, can now be achieved with MatPhos/Rh catalysts with ee values of 96-99 % for a variety of substrates at low catalyst loadings (0.1-1 mol %) and under mild conditions (5-20 bar H2, room temperature). After hydrolysis, the corresponding chiral secondary alkyl alcohols can be obtained in high enantiopurities providing a general and practical route to this important product class. Copyright
