1032818-10-2

Basic information

• Product Name: [2-bromo-1-(4-methylphenyl)ethyl]dimethylsulfonium bromide
• Synonyms: [2-bromo-1-(4-methylphenyl)ethyl]dimethylsulfonium bromide
• CAS NO: 1032818-10-2
• Molecular Weight: 340.122
• Mol File: 1032818-10-2.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: [2-bromo-1-(4-methylphenyl)ethyl]dimethylsulfonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: [2-bromo-1-(4-methylphenyl)ethyl]dimethylsulfonium bromide(1032818-10-2)
• EPA Substance Registry System: [2-bromo-1-(4-methylphenyl)ethyl]dimethylsulfonium bromide(1032818-10-2)

Safety Data

• Hazardous Substances Data: 1032818-10-2(Hazardous Substances Data)

Upstream product

• 622-97-9 1-ethenyl-4-methylbenzene 
• 50450-21-0 dimethylbromosulphonium bromide 
• 75-18-3 dimethylsulfide 

Downstream Products

• 1032817-96-1 1-cyclohexyl-2-p-tolylaziridine 
• 1254587-97-7 1-ethyl-2-(4-methylphenyl)aziridine 
• 57560-60-8 5-(p-tolyl)oxazolidin-2-one 
• 72583-44-9 3-methyl-5-(p-tolyl)oxazolidin-2-one 
• 1247948-60-2 3-ethyl-5-(4-methylphenyl)oxazolidin-2-one 
• 58777-94-9 1-methyl-2-(p-tolyl)aziridine 
• 1401693-85-3 1-(1-benzoyl-2-(p-tolyl)cyclopropyl)ethanone 
• 97467-11-3 6,6-dimethyl-2-(4-methylphenyl)-3,5,6,7-tetrahydro-1-benzofuran-4(2H)-one 
• 1381845-90-4 2-(4-methylphenyl)-3,5,6,7-tetrahydro-1-benzofuran-4(2H)-one 

Relevant articles and documents

Diastereoselective Construction of Cyclopropane-Fused Tetrahydroquinolines via a Sequential [4 + 2]/[2 + 1] Annulation Reaction

A sequential [4 + 2]/[2 + 1] annulation of α-aryl vinylsulfoniums with 2-aminochalcones and 2-(2-aminobenzylidene)-1H-indene-1,3(2H)-dione is reported that affords a series of cyclopropane-fused tetrahydroquinolines. The salient features of this novel and practical transformation include high efficiency, transition-metal-free nature, operational simplicity, and outstanding functional group tolerance.

Asymmetric Ring-Opening of Cyclopropyl Ketones with Thiol, Alcohol, and Carboxylic Acid Nucleophiles Catalyzed by a Chiral N,N′-Dioxide-Scandium(III) Complex

A highly efficient asymmetric ring-opening reaction of cyclopropyl ketones with a broad range of thiols, alcohols and carboxylic acids has been first realized by using a chiral N,N′-dioxide-scandium(III) complex as catalyst. The corresponding sulfides, ethers, and esters were obtained in up to 99 % yield and 95 % ee. This is also the first example of one catalytic system working for the ring-opening reaction of donor-acceptor cyclopropanes with three different nucleophiles, let alone in an asymmetric version.

A facile and regioselective multicomponent synthesis of chiral aryl-1,2-mercaptoamines in water followed by monoamine oxidase (MAO-N) enzymatic resolution

A facile microwave assisted three-component protocol allows the synthesis of chiral aryl-1,2-mercaptoamines in water in a few minutes with high yields, bypassing the use of toxic aziridine intermediates. The chiral 1,2-mercaptoamines were then deracemized through enzymatic resolution of the racemates using monoamine oxidase (MAO-N) biocatalysts.

Efficient Cycloaddition of CO2and Aziridines Activated by a Quadruple-Interpenetrated Indium-Organic Framework as a Recyclable Catalyst

On the basis of the global warming effect, it is of great significance to convert CO2 into the high value-added products oxazolidinones, but investigations on main-group-based metal-organic frameworks (MOFs) as heterogeneous catalysts still have not been