10335-98-5Relevant articles and documents
Sulfoxide and Sulfone Synthesis via Electrochemical Oxidation of Sulfides
Lee, Sunwoo,Park, Jin Kyu
, p. 13790 - 13799 (2021/10/12)
The oxidation of diaryl sulfides and aryl alkyl sulfides to the corresponding sulfoxides and sulfones under electrochemical conditions is reported. Sulfoxides are selectively obtained in good yield under a constant current of 5 mA for 10 h in DMF, while sulfones are formed as the major product under a constant current of 10 or 20 mA for 10 h in MeOH. The oxygen of both the sulfoxide and sulfone function is derived from water.
Diastereoselective radical alkylations of alkyl aryl sulfoxides
Zahouily, Mohamed,Caron, Giulia,Carrupt, Pierre-Alain,Knouzi, Nourdine,Renaud, Philippe
, p. 8387 - 8390 (2007/10/03)
1,2-Asymmetric induction in reactions of arylsulfinylated radicals has been examined and compared to the anionic processes. A rule of thumb allowing to predict the stereoselectivity is presented.