1034138-03-8Relevant articles and documents
Spirodiepoxide-based cascades: Direct access to diverse motifs
Sharma, Rojita,Manpadi, Madhuri,Zhang, Yue,Kim, Hiyun,Ahkmedov, Novruz G.,Williams, Lawrence J.
supporting information; experimental part, p. 3352 - 3355 (2011/08/22)
Allene epoxide formation/opening reaction sequences enabled direct access to diverse products. Described here are a single flask procedure for allene preparation and allene oxidation/derivatization reactions that give, among others, diendiol, diyndiol, α′-hydroxy-γ-enone, dihydrofuranone, butenolide, and δ-lactone products.
Stereospecific anti SE2′ fluorination of allenylsilanes: Synthesis of enantioenriched propargylic fluorides
Carroll, Laurence,McCullough, Samantha,Rees, Tom,Claridge, Timothy D. W.,Gouverneur, Veronique
supporting information; experimental part, p. 1731 - 1733 (2008/10/09)
The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereosp