103499-50-9

Upstream product

• 132904-91-7 ((2S,3R)-2,3,4-Tris-methoxymethoxy-pent-4-enyloxymethyl)-benzene 
• 103499-48-5 (2S,3S)-5-(benzyloxy)-3,4-bis<(methoxymethyl)oxy>-2-pentanol 
• 75-16-1 methylmagnesium bromide 
• 401479-97-8 (2R,3S)-4-Benzyloxy-2,3-bis-methoxymethoxy-butyric acid methyl ester 
• 151101-22-3 4-benzyloxy-(E)-but-2-enoic acid methyl ester 
• 132904-89-3 [2-Methoxymethoxy-1-(1-methoxymethoxy-vinyl)-allyloxy]-dimethyl-silane 
• 132904-90-6 (2S,3R)-2,4-Bis-methoxymethoxy-pent-4-ene-1,3-diol 
• 100-39-0 benzyl bromide 
• 401479-91-2 (2R,3S)-4-Benzyloxy-2,3-dihydroxy-butyric acid methyl ester 

Downstream Products

• 103616-05-3 (2S,3S,4S)-5-(benzyloxy)-3,4-bis<(methoxymethyl)oxy>-2-pentanol 
• 103499-48-5 (2R,3S,4S)-5-(benzyloxy)-3,4-bis<(methoxymethyl)oxy>-2-pentanol 

Relevant academic research and scientific papers

Influence of substitution pattern on intramolecular alkylidene carbene insertion reactions

A series of intramolecular alkylidene insertion reactions have been investigated. The nature of the substituents is demonstrated to have a dramatic effect on the outcome. In one example a novel rearrangement is observed.

Catalytic asymmetric intramolecular hydrosilation

Catalytic asymmetric intramolecular hydrosilation of di(2-propenyl)methanol in the presence of a Rh(I) complex containing (R,R)-DIOP or (R)-BINAP as ligand, followed by hydrogen peroxide oxidation, afforded optically active (2S,3R)-2,4-dimethyl-4-penume-1

α-Chelation Controlled Nucleophilic Addition to Chiral α,β-Dialkoxy Carbonyl Compounds. Diastereoselective Preparation of L-xylo and L-lyxo Triols

The Grignard reaction of 4-O-benzyl-2,3-O-bis(methoxymethyl)-L-threose (1) or 2,3-O-bis(methoxymethyl)-L-threo-furanose (4) with RMgX (R = Me, n-Pr, p-MeOC6H4, and p-MeOC6H4CH2) provided the chromatographically separable mixtures of the xylo and lyxo alco