1035458-32-2Relevant academic research and scientific papers
RhIII-Catalyzed Asymmetric Transfer Hydrogenation of Α-Methoxy Β-Ketoesters through DKR in Water: Toward a Greener Procedure
He, Bin,Zheng, Long-Sheng,Phansavath, Phannarath,Ratovelomanana-Vidal, Virginie
, p. 3032 - 3036 (2019)
The asymmetric reduction of α-methoxy β-ketoesters through transfer hydrogenation with a new rhodium(III) complex was developed. The reaction was efficient in 2-MeTHF with formic acid/triethylamine or in water with sodium formate. The corresponding syn α-
Lewis base activation of Lewis acids: Catalytic, enantioselective addition of glycolate-derived silyl ketene acetals to aldehydes
Denmark, Scott E.,Chung, Won-Jin
, p. 4582 - 4595 (2008/09/21)
(Chemical Equation Presented) A catalytic system involving silicon tetrachloride and a chiral, Lewis basic bisphosphoramide catalyst is effective for the addition of glycolate-derived silyl ketene acetals to aldehydes. It was found that the sense of diast
