103562-25-0

Basic information

• Product Name: [Rh(5,10,15,20-tetraphenylporphyrinato)(methyl)]
• Synonyms: [Rh(5,10,15,20-tetraphenylporphyrinato)(methyl)]
• CAS NO: 103562-25-0
• Molecular Weight: 730.673
• Mol File: 103562-25-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Rh(5,10,15,20-tetraphenylporphyrinato)(methyl)](CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(5,10,15,20-tetraphenylporphyrinato)(methyl)](103562-25-0)
• EPA Substance Registry System: [Rh(5,10,15,20-tetraphenylporphyrinato)(methyl)](103562-25-0)

Safety Data

• Hazardous Substances Data: 103562-25-0(Hazardous Substances Data)

Upstream product

• 69509-35-9 RhI(tetraphenylporphyrin) 
• 75-59-2 tetramethyl ammoniumhydroxide 
• 75-58-1 tertamethylammonium iodide 
• 2650-51-3 butyltrimethylammonium bromide 
• 3947-76-0 N-methylquinolinium iodide 

Relevant articles and documents

Alkylation of rhodium porphyrins using ammonium and quinolinium salts

Alkylation of rhodium(III) porphyrins [RhIII(por)] was achieved under relatively mild conditions in up to 98% yields, where readily available ammonium and quinolinium salts were utilized as the alkylating agents. This transformation tolerates air and water, thus serving as a convenient method to prepare a variety of alkyl- and benzyl-RhIII(por) complexes. Preliminary mechanistic studies support an SN2-like reaction pathway involving a RhI(por) anion intermediate.