{bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}

Base Information

Chemical Name:{bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}
CAS No.:103619-62-1
Molecular Formula:C₁₁Co₂MnO₁₀*C₃₆H₃₀NP₂
Molecular Weight:1003.63
Hs Code.:

Synonyms:{bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}

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Chemical Property of {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}

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Technology Process of {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}

There total 10 articles about {bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 52542-59-3
{bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5}

: bromomethylidynetricobalt nonacarbonyl

: 10170-69-1
dimanganese decacarbonyl

: 53433-12-8
[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Co(CO)4]

: 103619-62-1
{bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}

: 20545-30-6
bis(triphenylphosphoranylidene)ammonium bromide

Guidance literature:: In dichloromethane; Addn. of a soln. of (PPN)(Mn(CO)5) to a soln. of Co3(CO)9CBr (N2, stirring, room temp.), color changes from deep purple to brown.; Evapn., extn. (pentane) to remove Mn2(CO)10, extn. (ethyl acetate), filtering to remove PPNBr and PPNCo(CO)4, evapn., extn. (Et2O, i-Pr2O), concg., layering with pentane, brown crystals form by slow diffusion, filtering, drying in vac.;

Reference yield: 31.0%

: 53433-12-8
[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Co(CO)4]

: 86392-60-1
Mn(CO)5CBr₃

: 14516-54-2
bromopentacarbonylmanganese(I)

: 103619-62-1
{bis(triphenylphosphine)nitrogen}{manganese(cobalt)2(carbonyl)9(μ3-ketenylidene)}

: 22541-53-3,65860-59-5
cobalt(II)

Guidance literature:: In dichloromethane; byproducts: CO; Dissolving of freshly prepd. Mn(CO)5(CBr3) and (PPN)(Co(CO)4) in CH2Cl2 at -78°C under N2, warming (30 min, room temp.) until end of CO evolution.; Evapn., extn. of solid with hexane (4x) to remove Mn(CO)5Br, extn. (i-Pr2O) of remaining solid, filtering, layering with pentane, dark brown solid forms, filtering, washing (pentane), drying in vac., elem. anal.;