103628-86-0

Basic information

• Product Name: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl(allyl) ether
• Synonyms: 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-(2-propenyloxy)octane;3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl(allyl) ether
• CAS NO: 103628-86-0
• Molecular Formula: C11H9F13O
• Molecular Weight: 404.17
• Mol File: 103628-86-0.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 70 °C(Press: 20 Torr)
• Appearance: /
• Density: 1.429±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl(allyl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl(allyl) ether(103628-86-0)
• EPA Substance Registry System: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctyl(allyl) ether(103628-86-0)

Safety Data

• Hazardous Substances Data: 103628-86-0(Hazardous Substances Data)

Upstream product

• 647-42-7 1H,1H,2H,2H-tridecafluoro-n-octanol 
• 106-95-6 allyl bromide 
• 107-05-1 3-chloroprop-1-ene 

Relevant articles and documents

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A series of fluorinated polyhedral oligomeric silsesquioxane (POSS) derivatives were prepared via hydrosilylation reaction and they were characterized by 1H, 13C, 29Si and 19F nuclear magnetic resonance (NMR) sp

SYNTHESE D'ETHERS ET DE THIOETHERS ALLYLIQUES FLUORES PAR CATALYSE PAR TRANSFERT DE PHASE

Several fluorinated allylic ethers, thioethers and diethers have been prepared in excellent yields by phase transfer catalysis (CTP).The used halogenated compounds are allyl chloride and bromide, p-chloromethylstyrene.The used fluorinated alcohols are aromatic pentafluorophenol and various aliphatics: CF3-CH2OH, CF2H-CF2-CH2-OH, ClCF2-CF2-CH2OH, C6F13C2H4OH, HO-CH2-CF2-CFCl-CF2-CH2OH and HO-C6H4-C(CF3)2-C6H4-OH.All these new compounds have been characterized by 1H and 13C NMR.We conclude that CTP is the best method to obtain allylic and diallylic compounds.

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Production of allyl perfluoro alkyl ether

PROBLEM TO BE SOLVED: To provide a method for manufacturing high-purity allyl perfluoroalkyl ether by reducing the amount of unreacted perfluoro alkyl alcohol.SOLUTION: The method for manufacturing allyl perfluoroalkyl ether represented by the general formula of (2) R-(CH)-O-CH-CH=CHcomprises the reaction step of reacting perfluoro alkyl alcohol represented by the general formula of (1) R-(CH)-OH with allyl halide in the presence of solid alkali by agitating them at 1.3 times or more and 5 times or less of a particle floating limit agitation speed n(rpm) calculated by the following particle floating limit agitation speed formula of (I) n=60×S×νd(gΔρ/ρ)Xdin a reaction tank having an impeller.