103628-86-0Relevant articles and documents
Fluorinated polyhedral oligomeric silsesquioxanes
Wang, Xiaobai,Ye, Qun,Song, Jing,Cho, Ching Mui,He, Chaobin,Xu, Jianwei
, p. 4547 - 4553 (2015)
A series of fluorinated polyhedral oligomeric silsesquioxane (POSS) derivatives were prepared via hydrosilylation reaction and they were characterized by 1H, 13C, 29Si and 19F nuclear magnetic resonance (NMR) sp
Synthesis of new phosphonic derivatives with fluorinated chains
Brondino,Boutevin,Hervaud,Pelaprat,Manseri
, p. 193 - 200 (1996)
The synthesis of phosphonic derivatives (phosphonates and phosphonic acids) bearing fluorinated chains is presented. Such compounds with different spacers between these groups have been produced mainly by the telomerization of w-unsaturated phosphonic derivatives with fluorinated transfer agents such as mercaptans. The fluorinated phosphonates were quantitatively hydrolyzed to fluorinated phosphonic acids via two pathways: a classical one involving acids and another via silylation. Most products have been characterized by NMR and mass spectroscopy.
SYNTHESE D'ETHERS ET DE THIOETHERS ALLYLIQUES FLUORES PAR CATALYSE PAR TRANSFERT DE PHASE
Boutevin, B.,Youssef, B.,Boileau, S.,Garnault, A. M.
, p. 399 - 410 (1987)
Several fluorinated allylic ethers, thioethers and diethers have been prepared in excellent yields by phase transfer catalysis (CTP).The used halogenated compounds are allyl chloride and bromide, p-chloromethylstyrene.The used fluorinated alcohols are aromatic pentafluorophenol and various aliphatics: CF3-CH2OH, CF2H-CF2-CH2-OH, ClCF2-CF2-CH2OH, C6F13C2H4OH, HO-CH2-CF2-CFCl-CF2-CH2OH and HO-C6H4-C(CF3)2-C6H4-OH.All these new compounds have been characterized by 1H and 13C NMR.We conclude that CTP is the best method to obtain allylic and diallylic compounds.
Lip cosmetic
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Paragraph 0049; 0050, (2018/05/03)
PROBLEM TO BE SOLVED: To provide labial cosmetics causing no slipping on lips during their application and preventing color irregularity.SOLUTION: F/O emulsified labial cosmetics contain the following components (A), (B) and (C): (A) 0.1-10 mass% of porous organic powder with a specific surface area of 20-800 m/g, (B) 20-70 mass% of fluorine-based oil solutions in liquid form at 25°C, and (C) 10-70 mass% of oil solutions in liquid form at 25°C, excluding the component (B).
EMULSION COSMETIC
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Paragraph 0058-0059, (2017/09/13)
PROBLEM TO BE SOLVED: To provide an emulsion cosmetic which has a natural finish without whitish appearance and powderiness and is excellent in color unevenness-covering power to be a neat and bright finish without a thick finish. SOLUTION: An emulsion cosmetic contains following components (A) and (B): (A) 0.1-40 mass% of iron oxide-coated titanium oxide an average particle diameter of which is 0.05-0.5 μm in which 0.5-5 mass% of iron oxide is contained based on the mass of titanium oxide in the iron oxide-coated titanium oxide; and (B) 0.1-10 mass% of tabular powder an average particle diameter of which is 1-50 μm in which chroma C is 10 or more and a hue angle is 120-190° regulated by CIE1976 L*a*b* color system when the powder is evenly coated on a black artificial leather to be 8 mg/100 cm2 and color of a regular reflection (incident light angle 45° and acceptance angle -45°) is measured. SELECTED DRAWING: None COPYRIGHT: (C)2017,JPOandINPIT
WATER-IN-OIL EMULSION TYPE COSMETIC
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Paragraph 0050, (2017/11/16)
PROBLEM TO BE SOLVED: To provide a water-in-oil type emulsion cosmetic which forms a soft cosmetic film after application, has excellent followability to the skin, causes no filmy feeling, causes no finger marks even when a cosmetic coating after application is pressed and prevents peeling off of a cosmetic film. SOLUTION: There is provided a water-in-oil type emulsion cosmetic which comprises: (A) 0.01 to 20 mass% of a fluorine-modified silicone resin which is solid at 25°C represented by the following formula (1); (B) 0.01 to 50 mass% of a fluorine-modified silicone oil which is solid at 25°C having a polysiloxane unit represented by the following formulas (2) and (3); (C) 0.1 to 10 mass% of octyl p-methoxycinnamate; and (D) 0.01 to 3 mass% of iron oxide and/or titanium oxide. R11gSiO(4-g)/2 (1) (R11 represents hydrocarbon, phenyl, OH, perfluoroalkyl or the like; g represents an average number and satisfies the following expression, 1.0≤g≤1.8) (Rf2 represents a linear or branched perfluoroalkyl having 6 carbon atoms; R21 to R23 represent a hydrocarbon having 1 to 6 carbon atoms; m represents 2 to 6; n represents 1 to 6; p represents 3 to 50; s represents 1 to 5.) SELECTED DRAWING: None COPYRIGHT: (C)2017,JPO&INPIT
Production of allyl perfluoro alkyl ether
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Paragraph 0048; 0049, (2017/12/01)
PROBLEM TO BE SOLVED: To provide a method for manufacturing high-purity allyl perfluoroalkyl ether by reducing the amount of unreacted perfluoro alkyl alcohol.SOLUTION: The method for manufacturing allyl perfluoroalkyl ether represented by the general formula of (2) R-(CH)-O-CH-CH=CHcomprises the reaction step of reacting perfluoro alkyl alcohol represented by the general formula of (1) R-(CH)-OH with allyl halide in the presence of solid alkali by agitating them at 1.3 times or more and 5 times or less of a particle floating limit agitation speed n(rpm) calculated by the following particle floating limit agitation speed formula of (I) n=60×S×νd(gΔρ/ρ)Xdin a reaction tank having an impeller.
Water-in-oil emulsion cosmetic
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Paragraph 0071, (2017/06/08)
PROBLEM TO BE SOLVED: To provide a water-in-oil type emulsion cosmetic in which unevenness and powderiness are not caused on a skin, makeup does not become thick, and natural finish is obtained, and feeling of being caught at the time of initial application and feeling of stiffness are suppressed.SOLUTION: A water-in-oil type emulsion cosmetic contains following components (A), (B), and (C): (A) 0.3-25 mass% of a polymer powder which includes an inorganic pigment and contains (a) a white inorganic pigment, (b) a red inorganic pigment, and (c) a yellow inorganic pigment, and in which a mass ratio of (a):(b):(c) is 70-99:0.1-10:0.1-20; (B) 0.01-50 mass% of a fluorine modified silicone which has a polysiloxane unit represented by general formula (1) and (2); (C) 0.1-15 mass% of particulate zinc oxide with a specific surface area of 10-100 m/g. A mass ratio (A)/(B) of the component (A) to the component (B) is 0.03-10.
Production of [...]
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Paragraph 0037-0039, (2017/06/02)
PROBLEM TO BE SOLVED: To provide a method for highly efficient producing allyl fluoroalkyl ether without corroding a reaction tank.SOLUTION: Provided is a method for producing allyl fluoroalkyl ether represented by the following general formula (1) comprising: a reaction step of reacting a fluoroalkyl alcohol represented by the following general formula (2) and allyl halide in a reaction vessel made of stainless steel in the absence of a solvent and in the presence of an alkali; a water washing step following the reaction step, to remove the alkali and an alkali salt by washing with water; and an allyl halide removing step following the water washing step, to remove a residual ally halide: R-(CH)-O-CH-CH=CH(1); and R-(CH)-OH (2), wherein Rrepresents a perfluoroalkyl group having 1 to 6 carbon atoms and n represents an integer of 1 to 6.
Water-in-oil emulsion cosmetic
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Paragraph 0080-0081, (2017/06/24)
PROBLEM TO BE SOLVED: To provide a water-in-oil emulsion cosmetic which provides soft and moist feeling and is free of rough texture when the skin is pressed by a finger after applying the cosmetic, does not stay thick on a skin, and has a reduced occurrence of dullness of the skin over time.SOLUTION: A water-in-oil emulsion cosmetic includes the following ingredients (A), (B), and (C): (A) 0.1-30 mass% of a vinyl polymer having carbosiloxane dendrimer structure at its side chain; (B) a powder which has been surface treated by tridecafluorooctyltriethoxysilane; and (C) 0.01-50 mass% of a fluorine-modified silicone having a polysiloxane unit represented by the general formulas (3) and (4). The mass ratio of the ingredient (A) and the ingredient (B) is (A)/(B)=0.003-10.
