10363-70-9Relevant academic research and scientific papers
Transition-Metal-Free C-S Bond Formation: Aqueous Synthesis of S-Aryl Dithiocarbamates by the use of Stable Arenediazonium Salts Mediated by Nano-Magnetic Supported Silica Sulfonic Acid
Nemati, Firouzeh,Elhampour, Ali,Zulfaghari, Soghra
, p. 1692 - 1702 (2015)
A convenient and transition-metal-free method for the synthesis of S-aryl dithiocarbamates based on the reaction of stable arenediazonium nano-magneto silica sulfates (ArN2+-OSO3-SiO2@Fe3O4) with dithiocarbamic acid at room temperature was studied. Avoiding the use of any hazardous transition metal, simple procedure, low cast, and short reaction time are noteworthy advantages of this methodology.
Transition metal-free procedure for the synthesis of S-aryl dithiocarbamates using aryl diazonium fluoroborate in water at room temperature
Chatterjee, Tanmay,Bhadra, Sukalyan,Ranu, Brindaban C.
experimental part, p. 1837 - 1842 (2011/10/01)
A convenient, efficient and green procedure for the synthesis of S-aryl dithiocarbamates has been developed by a simple one-pot condensation of aryl diazonium fluoroborate, carbon disulfide and amine in the absence of any transition metal catalyst in water at room temperature. The reactions of a variety of substituted aryl diazonium fluoroborates, and cyclic and open chain amines, have been addressed. The products are purified by crystallization from ethanol and the process does not involve any hazardous solvent.
