103683-08-5Relevant articles and documents
Neighbouring Group Participation by the Vinyl Group in Reactions of Sterically-hindered Organosilicon Compounds
Ayoko, G. Adefikayo,Eaborn, Colin
, p. 630 - 631 (1986)
Anchimeric assistance by the γ-vinyl group makes (Me3Si)2C(SiMe2CH=CH2)(SiMe2I) much more reactive than (Me3Si)3CSiMe2I towards CF3CH2OH, CF3CO2H, and silver salts, and treatment of (Me3Si)2C(SiMe2CH=CH2)(SiEt2I) with AgO2CCF3 or AgBF4 gives mixtures of (
Anchimeric Assistance by and Migration of the Vinyl Group in Reactions of Sterically Hindered Organosilicon Compounds of the Type (Me3Si)2C(SiMe2CH=CH2)(SiR2X)
Ayoko, G. Adefikayo,Eaborn, Colin
, p. 1047 - 1058 (2007/10/02)
The compound VsiSiMe2I (1) is very similar in reactivity to (Me3Si)3CSiMe2I (2) in reaction with methanol and with alkali-metal salts in MeOH or MeCN, but (1) is much the more reactive towards electrophiles which induce rate-d