Neighbouring Group Participation by the Vinyl Group in Reactions of Sterically-hindered Organosilicon Compounds

DOI: 10.1039/c39860000630

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Journal of the Chemical Society. Chemical communications p. 630 - 631 (1986)

Update date:2022-08-28

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Authors:

Ayoko, G. Adefikayo

Eaborn, Colin

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Article abstract of DOI:10.1039/c39860000630

Anchimeric assistance by the γ-vinyl group makes (Me3Si)2C(SiMe2CH=CH2)(SiMe2I) much more reactive than (Me3Si)3CSiMe2I towards CF3CH2OH, CF3CO2H, and silver salts, and treatment of (Me3Si)2C(SiMe2CH=CH2)(SiEt2I) with AgO2CCF3 or AgBF4 gives mixtures of (

Full text of DOI:10.1039/c39860000630

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