103702-71-2

Upstream product

• 100-51-6 benzyl alcohol 
• 4348-68-9 2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl bromide 
• 1824-96-0 Methyl α-lyxofuranoside 
• 98-88-4 benzoyl chloride 
• 56271-35-3 2,3,5-tri-O-benzoyl-α,β-D-arabinofuranosyl bromide 
• 7473-42-9 methyl tri-O-benzoyl-α-D-arabinofuranoside 
• 79083-42-4 methyl D-arabinofuranoside 
• 532-20-7 D-arabinofuranose 
• 1431370-34-1 3,5-di-O-benzoyl-β-D-arabinofuranoside-prop-2-ynyl-1,2-orthobenzoate 

Downstream Products

• 64609-17-2 benzyl α-D-arabinofuranoside 
• 878288-79-0 benzyl 2-O-benzyl-α-D-arabinofuranoside 
• 878288-81-4 benzyl 2-O-benzyl-α-D-arabinofuranoside-3,5-cyclic sulfide 
• 878288-82-5 benzyl 3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-α-D-arabinofuranoside 
• 878288-83-6 benzyl 2-O-benzyl-3,5-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-α-D-arabinofuranoside 
• 878288-87-0 benzyl 2-O-benzyl-5-deoxy-5-[2,3,5-tri-O-benzyl-1,4-dideoxy-1,4-episulfoniumylidene-D-arabinitol]-3-O-sulfoxy-α-D-arabinofuranose inner salt 

Relevant academic research and scientific papers

Gold(III)-catalyzed glycosidations for 1,2- trans and 1,2- cis furanosides

Stereoselective synthesis of furanosides is still a daunting task, unlike the pyranosides, for which several methods exist. Herein, a unified stereoselective strategy for the synthesis of 1,2-trans and 1,2-cis furanosides is revealed for seven out of eight possible isomers of pentoses. The identified protocol gives access to diastereoselective synthesis of α- and β-araf, ribf, lyxf, and α-xylf furanosides. 1,2-trans glycosides were synthesized by the use of propargyl 1,2-orthoesters under gold-catalyzed glycosidation conditions, and subsequently, they are converted into 1,2-cis glycosides through oxidation-reduction as the key functional group transformation. All the reactions are found to be fully diastereoselective, mild, and high yielding.

Facile synthesis of β- And α-arabinofuranosides and application to cell wall motifs of M. tuberculosis

Propargyl 1,2-orthoesters of arabinose are exploited for the synthesis of 1,2-trans furanosides; easily accessible 1,2-trans ribofuranosides are converted to challenging 1,2-cis-arabinofuranosides by oxidoreduction. Utility of these protocols was demonstrated by the successful synthesis of major structural motifs present in the cell surface of Mycobacterium tuberculosis. Key furanosylations were carried out under gold-catalyzed glycosidation conditions.

Synthesis of sulfonium sulfate analogues of disaccharides and their conversion to chain-extended homologues of salacinol: New glycosidase inhibitors

Four chain extended homologues of salacinol, a naturally occurring glycosidase inhibitor, were prepared for evaluation as inhibitors of glucosidase enzymes involved in the breakdown of carbohydrates. The syntheses involved the reactions of 1,4-anhydro-2,3