7473-42-9

Basic information

• Product Name: METHYL-2,3,5-TRI-O-BENZOYL-A-D-*ARABINOFURANOSIDE
• Synonyms: METHYL-2,3,5-TRI-O-BENZOYL-A-D-*ARABINOFURANOSIDE;1-O-METHYL-2,3,5-TRI-O-BENZOYL-ALPHA-D-ARABINOFURANOSIDE;.alpha.-D-Arabinofuranoside, methyl, tribenzoate;1-O-METHYL-2,3,5-TRI-O-BENZOYL-A-D-ARABINOFURANOSIDE;Methyl 2,3,5-tri-O-benzoyl-α-D-arabinofuranoside;Nsc400281;Methyl 2,3,5-Tri-O-benzoyl -α-D-arabinoside;Methyl α-D-Arabinofuranoside Tribenzoate
• CAS NO: 7473-42-9
• Molecular Formula: C₂₇H₂₄O₈
• Molecular Weight: 476.47466
• Product Categories: Carbohydrates & Derivatives
• Mol File: 7473-42-9.mol
• Article Data: 7

Chemical Properties

• Melting Point: 98-100°C
• Boiling Point: 598.8°Cat760mmHg
• Flash Point: 256.1°C
• Appearance: /
• Density: 1.32g/cm³
• Vapor Pressure: 2.68E-14mmHg at 25°C
• Refractive Index: 1.608
• Storage Temp.: 2-8°C
• Solubility: Chloroform (Slightly), Methanol (Very Slightly, Heated)
• CAS DataBase Reference: METHYL-2,3,5-TRI-O-BENZOYL-A-D-*ARABINOFURANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL-2,3,5-TRI-O-BENZOYL-A-D-*ARABINOFURANOSIDE(7473-42-9)
• EPA Substance Registry System: METHYL-2,3,5-TRI-O-BENZOYL-A-D-*ARABINOFURANOSIDE(7473-42-9)

Safety Data

• Hazardous Substances Data: 7473-42-9(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Uses

Different sources of media describe the Uses of 7473-42-9 differently. You can refer to the following data:
1. Used in the preparation of 1-α- and 1-β-D-Arabinofuranosyl-2-nitroimidazole (α-AZA and β-AZA) as synthons for a number of potential markers of tissue hypoxia.
2. Methyl-2,3,5-tri-O-benzoyl-alpha-D-arabinofuranoside is used in the preparation of 1-α- and 1-β-D-Arabinofuranosyl-2-nitroimidazole (α-AZA and β-AZA) as synthons for a number of potential markers of tissue hypoxia.

InChI:InChI=1/C27H24O8/c1-31-27-23(35-26(30)20-15-9-4-10-16-20)22(34-25(29)19-13-7-3-8-14-19)21(33-27)17-32-24(28)18-11-5-2-6-12-18/h2-16,21-23,27H,17H2,1H3

Upstream product

• 67-56-1 methanol 
• 70051-90-0 tri-O-benzoyl-β-D-arabinofuranosyl bromide 
• 4348-68-9 2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl bromide 
• 25545-03-3 β-D-arabinofuranose 
• 1824-96-0 Methyl α-lyxofuranoside 
• 98-88-4 benzoyl chloride 
• 79083-42-4 methyl D-arabinofuranoside 
• 28697-53-2 D-arabinopyranose 
• 532-20-7 D-arabinofuranose 
• 56607-40-0 methyl D-arabinofuranoside 
• 10323-20-3 D-Arabinose 

Downstream Products

• 915149-97-2 1-O-(2-O-benzoyl-3,5-di-O-benzyl-α-D-arabinofuranosyl) trichloroacetimidate 
• 915149-98-3 1-O-(2-O-benzoyl-3-O-levulinoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl) trichloroacetimidate 
• 915150-26-4 pent-4-enyl 5-O-{5-O-[2-O-benzoyl-5-O-(triisopropylsilyl)-α-D-arabinofuranosyl]-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranosyl}-2-O-benzoyl-3-O-benzyl-α-D-arabinofuranoside 
• 915150-25-3 C₆₉H₈₄O₁₈Si 
• 56271-35-3 2,3,5-tri-O-benzoyl-α,β-D-arabinofuranosyl bromide 
• 1276043-29-8 3,5-di-O-benzoyl-β-D-lyxofuranose-1,2-(pent-4-enyl orthobenzoate) 
• 1379681-51-2 3,5-di-O-benzoyl-1,2-bis-O-(chloroacetyl)-D-arabinofuranose 
• 1379681-41-0 3,5-di-O-benzoyl-1,2-bis-O-(chloroacetyl)-D-arabinofuranose 
• 76612-55-0 1,2-di-O-acetyl-3,5-di-O-benzoyl-D-arabinofuranose 
• 1379681-42-1 phenyl 2-O-acetyl-3,5-di-O-benzoyl-1-thio-α-D-arabinofuranoside 
• 1379681-43-2 phenyl 3,5-di-O-benzoyl-1-thio-α-D-arabinofuranoside 

Relevant articles and documents

Preparation of the tri-arabino di-mycolate fragment of mycobacterial arabinogalactan from defined synthetic mycolic acids

An efficient synthetic approach to tri-arabino di-mycolates, using structurally defined synthetic α-, keto and methoxy mycolic acids is described.

Automated solid phase synthesis of oligoarabinofuranosides

Automated solid phase synthesis enables rapid access to the linear and branched arabinofuranoside oligosaccharides. A simple purification step is sufficient to provide the conjugation ready oligosaccharides in good yield.

A one-pot synthesis of 1-α- and 1-β-d-arabinofuranosyl-2- nitroimidazoles: Synthons to the markers of tumor hypoxia

1-α- and 1-β-D-Arabinofuranosyl-2-nitroimidazole (α-AZA and β-AZ A) are synthons for a number of potential markers of tissue hypoxia. A one pot synthesis in which 2-nitroimidazole is coupled with a mixture of α-and β-1-O-acetyl-2,3,5-tri-O-benzoyl-D-arabi