103795-13-7

Upstream product

• 79265-30-8 2-(trimethylsilyl)thiazole 
• 103795-12-6 (R)-2-(benzyloxy)-2-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]acetaldehyde 
• 100-39-0 benzyl bromide 
• 103795-09-1 2-[((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-trimethylsilanyloxy-methyl]-thiazole 
• 103795-11-5 (1R)-1-O-benzyl-2,3-O-isopropylidene-1-(2-thiazolyl)-D-glycitol 
• 118377-11-0 2-[(R)-Benzyloxy-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-3-methyl-thiazol-3-ium; iodide 
• 103795-10-4 (2R,3R)-1,2-O-Isopropylidene-3-(2-thiazolyl)-1,2,3-propanetriol 
• 118377-12-1 2-[(R)-Benzyloxy-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-3-methyl-thiazolidine 
• 1027313-49-0 (R)-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-(3-methyl-thiazolidin-2-yl)-methanol 

Downstream Products

• 142760-39-2 (1S,2R,3R)-2-O-benzyl-3,4-O-isopropylidene-1-(2-thiazolyl)-1,2,3,4-butanetetraol 
• 103795-14-8 (1R)-2-O-benzyl-3,4-O-isopropylidene-1-(2-thiazolyl)-D-erythritol 
• 103795-26-2 (1R)-2,3,4,5-tetra-O-benzyl-6,7-O-isopropylidene-1-(2-thiazolyl)-D-allo-D-glycero-heptitol 
• 103795-26-2 (1S,2S,3S,4R,5R)-2,3,4,5-Tetrakis-benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-thiazol-2-yl-pentan-1-ol 
• 103795-22-8 (1R)-2,3,4-tri-O-benzyl-5,6-O-isopropylidene-1-(2-thiazolyl)-D-allitol 
• 103795-22-8 (1S,2S,3S,4R)-2,3,4-Tris-benzyloxy-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-thiazol-2-yl-butan-1-ol 
• 103795-18-2 (1R)-2,3-di-O-benzyl-3,4-O-isopropylidene-1-(2-thiazolyl)-D-ribitol 
• 103795-18-2 (1S,2S,3R)-2,3-Bis-benzyloxy-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-thiazol-2-yl-propan-1-ol 
• 103795-16-0 2,3-di-O-benzyl-4,5-O-isopropylidene-D-ribose 
• 103795-30-8 (1R)-2,3,4,5,6-penta-O-benzyl-7,8-O-isopropylidene-1-(2-thiazolyl)-D-allo-D-erythro-octitol 
• 103795-30-8 (1S,2S,3S,4S,5R,6R)-2,3,4,5,6-Pentakis-benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-thiazol-2-yl-hexan-1-ol 
• 103795-29-5 2-[(1R,2R,3R,4R,5R,6R)-2,3,4,5,6-Pentakis-benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-trimethylsilanyloxy-hexyl]-thiazole 
• 103795-27-3 (1R)-1,2,3,4,5-penta-O-benzyl-6,7-O-isopropylidene-1-(2-thiazolyl)-D-allo-D-glycero-heptitol 
• 103795-25-1 2-[(1R,2R,3R,4R,5R)-2,3,4,5-Tetrakis-benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-trimethylsilanyloxy-pentyl]-thiazole 

Relevant academic research and scientific papers

Iterative, Stereoselective Homologation of Chiral Polyalkoxy Aldehydes Employing 2-(Trimethylsilyl)thiazole as a Formyl Anion Equivalent. The Thiazole Route to Higher Carbohydrates

A new approach to long-chain sugars is demonstrated by the stereoselective conversion of D-glyceraldehyde acetonide (2a), L-threose acetonide (2b), and dialdogalactopyranose diacetonide (2h) into higher homologues up to C9, C7, and C

DIASTEREOSELECTIVITY IN THE 1,2-ADDITION OF SILYLAZOLES TO CHIRAL ALDEHYDES. STEREOCONTROLLED HOMOLOGATION OF α-HYDROXYALDEHYDES.

The addition of 2-trimethylsilylazoles (thiazole, benzothiazole, oxazole) to α-asymmetryc aldehydes give the corresponding O-silylcarbinols in good chemical yield and high stereoselectivity; the reaction is employed for the stereoselective homologation of