103795-16-0

Upstream product

• 100-39-0 benzyl bromide 
• 103795-14-8 (1R)-2-O-benzyl-3,4-O-isopropylidene-1-(2-thiazolyl)-D-erythritol 
• 7152-47-8 D-ribose diethyl dithioacetal 
• 103795-13-7 2-[(1R,2R)-2-Benzyloxy-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-trimethylsilanyloxy-ethyl]-thiazole 
• 118377-12-1 2-[(R)-Benzyloxy-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-3-methyl-thiazolidine 
• 103795-09-1 2-[((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-trimethylsilanyloxy-methyl]-thiazole 
• 112995-79-6 4,5-O-isopropylidene-D-ribose propane-1,3-diyl dithioacetal 
• 112995-78-5 D-ribose propane-1,3-diyl dithioacetal 
• 50-69-1 D-ribose 
• 103795-10-4 (2R,3R)-1,2-O-Isopropylidene-3-(2-thiazolyl)-1,2,3-propanetriol 
• 118377-11-0 2-[(R)-Benzyloxy-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-3-methyl-thiazol-3-ium; iodide 
• 103795-15-9 (1R)-1,2-di-O-benzyl-3,4-O-isopropylidene-1-(2-thiazolyl)-D-erythritol 
• 103795-11-5 (1R)-1-O-benzyl-2,3-O-isopropylidene-1-(2-thiazolyl)-D-glycitol 
• 25572-71-8 4,5-O-isopropylidene-D-ribose diethyl dithioacetal 

Downstream Products

• 112995-81-0 6,7-di-O-benzyl-8,9-O-isopropylidene-1,3,4,5-tetradeoxy-D-ribo-non-4-eno-2-ulose ethylene acetal 
• 103795-26-2 (1S,2S,3S,4R,5R)-2,3,4,5-Tetrakis-benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-thiazol-2-yl-pentan-1-ol 
• 103795-22-8 (1S,2S,3S,4R)-2,3,4-Tris-benzyloxy-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-thiazol-2-yl-butan-1-ol 
• 103795-18-2 (1R)-2,3-di-O-benzyl-3,4-O-isopropylidene-1-(2-thiazolyl)-D-ribitol 
• 103795-18-2 (1S,2S,3R)-2,3-Bis-benzyloxy-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-thiazol-2-yl-propan-1-ol 
• 103795-30-8 (1S,2S,3S,4S,5R,6R)-2,3,4,5,6-Pentakis-benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-thiazol-2-yl-hexan-1-ol 
• 103795-29-5 2-[(1R,2R,3R,4R,5R,6R)-2,3,4,5,6-Pentakis-benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-trimethylsilanyloxy-hexyl]-thiazole 
• 103795-27-3 (1R)-1,2,3,4,5-penta-O-benzyl-6,7-O-isopropylidene-1-(2-thiazolyl)-D-allo-D-glycero-heptitol 
• 103795-25-1 2-[(1R,2R,3R,4R,5R)-2,3,4,5-Tetrakis-benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-trimethylsilanyloxy-pentyl]-thiazole 
• 103795-32-0 (2R,3R,4R,5S,7R)-3,4,5,6-Tetrakis-benzyloxy-7-thiazol-2-yl-heptane-1,2,7-triol 
• 103795-23-9 (1R)-1,2,3,4-tetra-O-benzyl-5,6-O-isopropylidene-1-(2-thiazolyl)-D-allitol 
• 103795-21-7 2-[(1R,2R,3R,4R)-2,3,4-Tris-benzyloxy-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-trimethylsilanyloxy-butyl]-thiazole 
• 103795-34-2 (2R,3R,4R,5S,7S)-3,4,5,6-Tetrakis-benzyloxy-octane-1,2,7,8-tetraol 
• 118377-25-6 (2R,4S,5R,6R,7R)-3,4,5,6-Tetrakis-benzyloxy-2,7,8-trihydroxy-octanal 

Relevant academic research and scientific papers

Preparation of 2,5-anhydrohexitols (part I). Silicon-directed stereocontrolled cyclization

Stereoselective chain-extension of carbohydrate aldehydes with the hydroxymethylating reagent (dimethylphenylsilyl)methylmagnesium chloride (1) followed by acid-mediated cyclization gives access to 2,5-anhydro-hexitols. The stereoselectivity of the ring closure depends on the nature of the acid, i.e., treatment with excess BF3·Et2O or catalytic H2SO4 leads to tetrahydrofurans with 2,3-cis or 2,3-trans configuration, respectively. Concomitant elimination is effectively suppressed in case of cyclisation of the more sterically hindered isopropyl substituted silanes.

Cycloaddition Reactions of Carbohydrate Derivatives. Part V. A Hetero Diels-Alder Approach to Swainsonine Analogs

Diastereoselective hetero Diels-Alder reactions of sugar derived azomethines 4a-4g have been used for the construction of chiral piperidones 6 and 7.Configuration of the major products was 6,1'-threo in every case.The enone system of 6 and 7 was reduced d

Construction of all O-alkoxy D-tetrose and D-pentose stereoisomers from 2,3-O-isopropylidene-D-glyceraldehyde using 2-(trimethylsilyl)thiazole as a formyl anion equivalent

All D-tetroses and D-pentoses having differentially protected hydroxy groups are synthesized by an iterative one-carbon chain-elongation cycle commencing with the addition of 2-(trimethylsilyl)thiazole to 2,3-O-isopropylidene-D-glyceraldehyde. One half of

Iterative, Stereoselective Homologation of Chiral Polyalkoxy Aldehydes Employing 2-(Trimethylsilyl)thiazole as a Formyl Anion Equivalent. The Thiazole Route to Higher Carbohydrates

A new approach to long-chain sugars is demonstrated by the stereoselective conversion of D-glyceraldehyde acetonide (2a), L-threose acetonide (2b), and dialdogalactopyranose diacetonide (2h) into higher homologues up to C9, C7, and C

Chiral building units from carbohydrates-XIII. Identification of the absolute configuration of endo-brevicomin from dendroctonus frontalis and synthesis of both enantiomers from d-ribose

The synthesis of both enantiomers of endo-7-ethyl-5-methyl-6,8-dioxabicyclo[3.2.l]octana (endo-brevicomin, 12 and 12a) starting froni D-ri-bose is described. Key interinediate is the open chain derivative 7, a chiral building unit easily available from ca