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103826-50-2

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103826-50-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 103826-50-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,3,8,2 and 6 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 103826-50:
(8*1)+(7*0)+(6*3)+(5*8)+(4*2)+(3*6)+(2*5)+(1*0)=102
102 % 10 = 2
So 103826-50-2 is a valid CAS Registry Number.

103826-50-2Relevant articles and documents

Fine tuning of the sheet distance of graphene oxide that affects the activity and substrate selectivity of a Pd/graphene oxide catalyst in the Heck reaction

Saito, Akinori,Yamamoto, Shun-Ichi,Nishina, Yuta

, p. 59835 - 59838 (2014)

The interlayer distance of graphene oxide (GO) in a Pd/GO composite could be tuned using cationic surfactants. The distance becomes larger when a large surfactant is used. The catalytic activity in Heck reactions dramatically improved using the surfactant-modified Pd/GO catalyst. Substrate selectivity could also be improved by adjusting the size of the surfactant to increase accessibility of substrates to the active catalytic centre.

Controlled synthesis of uniform palladium nanoparticles on novel micro-porous carbon as a recyclable heterogeneous catalyst for the Heck reaction

Song, Kunpeng,Liu, Peng,Wang, Jingyu,Pang, Lei,Chen, Jian,Hussain, Irshad,Tan, Bien,Li, Tao

, p. 13906 - 13913 (2015)

Novel dual-porous carbon-supported palladium nanoparticle (Pd NP) catalysts were prepared by sequential carbonization and reduction of microporous organic polymer-encaged PdCl2. The diverse pore structure of microporous organic polymers provides a reservoir for the palladium precursors and prevents Pd NPs from sintering during the carbonization and reaction. The microporous structure has a significant effect on the size and dispersion of palladium NPs. The average size of the Pd NPs (in the range of 4-6 nm) was tuned by changing the pore size distribution and the carbonization temperature. The resulting carbon-supported Pd NPs were characterized by TEM, BET, XRD, and XPS and the Pd loading was calculated by AAS. The encaged Pd NP catalysts prepared by this methodology exhibited outstanding stability and reusability in the Heck reaction and could be reused at least 10 times without appreciable loss of activity.

Palladacycles bearing pendant benzamidinate ligands as catalysts for the Suzuki and Heck coupling reactions

Wu, Kai-Min,Huang, Chi-An,Peng, Kuo-Fu,Chen, Chi-Tien

, p. 9679 - 9687 (2005)

Three pendant benzamidines [Ph-C(NC6H5)-{NH(CH 2)2NMe2}] (1), [Ph-C(NC6H 5)-{NH(CH2Py)}] (2) and [Ph-C(NC6H 5)-{NH(o-C6H4)(oxazoline)}] (3) are described. Reactions of 1, 2 or 3 with one molar equivalent of Pd(OAc)2 in THF give the palladacyclic complexes [Ph-C{-NH(η1-C6H 4)}{N(CH2)2NMe2}]Pd(OAc) (4), [Ph-C{-NH(η1-C6H4)}{N (CH 2Py)}]Pd(OAc) (5) and [Ph-C{-NH(η1-C6H 4)}{N(o-C6H4)(oxazoline)}]Pd(OAc) (6), respectively. Treatment of 4, 5 or 6 with excess of LiCl in chloroform affords [Ph-C{-NH(η1-C6H4)}{N(CH2) 2NMe2}]PdCl (7), [Ph-C{-NH(η1-C 6H4)}{N(CH2Py)}]PdCl (8) and [Ph-C{-NH(η1-C6H4)}{N(o-C6H 4)(oxazoline)}]PdCl (9). The crystal and molecular structures are reported for compounds 1, 3, 5, 6 and 7. The application of these palladacyclic complexes to the Suzuki and Heck coupling reactions was examined.

Ligand-free (: Z)-selective transfer semihydrogenation of alkynes catalyzed by in situ generated oxidizable copper nanoparticles

Grela, Karol,Kusy, Rafa?

, p. 5494 - 5502 (2021/08/16)

Herein, we present (Z)-selective transfer semihydrogenation of alkynes based on in situ generated CuNPs in the presence of hydrogen donors, such as ammonia-borane and a green protic solvent. This environmentally friendly method is characterized by operational simplicity combined with high stereo- and chemoselectivity and functional group compatibility. Auto-oxidation of CuNPs after the completion of a semihydrogenation reaction results in the formation of a water-soluble ammonia complex, so that the catalyst may be reused several times by simple phase-separation with no need for any special regeneration processes. Formed NH4B(OR)4 can be easily transformed back into ammonia-borane or into boric acid. In addition, a one-pot tandem sequence involving a Suzuki reaction followed by semihydrogenation was presented, which allows minimization of chemical waste production.

Mesoporous silica nanospheres supported atomically precise palladium nanocluster: Highly efficient and recyclable catalysts in the reduction of 4-nitrophenol and Heck reactions

Gao, Taiping,Kang, Zhenlu,Zhao, Yining,Zhou, Yilin

, (2021/12/14)

Atomically precise palladium nanoclusters show great potential applications in the field of catalysis owing to its ultrasmall size and precise structure. This work, we report the mesoporous silica nanoparticles (MSNs) supported [Pd3Cl(PPh3)3(PPh2)2]Cl catalysts (denoted as Pd3Cl/MSNs) for the reduction of 4-nitrophenol and Heck coupling reactions of iodobenzene and styrenes. High uniform MSNs, with average diameter ≈110 nm, were prepared by sol–gel method, followed by Pd nanoclusters immobilization into the pore of MSNs. The MSNs supported Pd nanoclusters were well characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR), and diffuse reflectance optical spectrum. The results indicated that Pd3Cl nanoclusters after immobilized into the pores of MSNs are intact and possess good dispersibility. The catalytic performance of as-prepared nanocomposites was evaluated by the reduction of 4-nitrophenol and Heck reactions. The 4-nitrophenol could be completely conversion to 4-aminophenol within 6?min. Meanwhile, the as-prepared Pd3Cl/MSNs exhibit excellent catalytic performance in the Heck reactions between iodobenzenes and styrenes. The high catalytic activity of Pd3Cl/MSNs could be attributed to the large surface area and unique geometric structure of as-prepared Pd nanoclusters. More importantly, the catalysts could be easily recycled by centrifugation and shows excellent reusability.

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