10385-08-7

Basic information

• Product Name: N,N-diethylheptanamide
• CAS NO: 10385-08-7
• Molecular Formula: C₁₁H₂₃NO
• Molecular Weight: 185.3064
• Mol File: 10385-08-7.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 246.6°C at 760 mmHg
• Flash Point: 92.5°C
• Density: 0.863g/cm³
• Vapor Pressure: 0.0268mmHg at 25°C
• Refractive Index: 1.442
• CAS DataBase Reference: N,N-diethylheptanamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diethylheptanamide(10385-08-7)
• EPA Substance Registry System: N,N-diethylheptanamide(10385-08-7)

Safety Data

• Hazardous Substances Data: 10385-08-7(Hazardous Substances Data)

Upstream product

• 111-14-8 oenanthic acid 
• 109-89-7 diethylamine 
• 106-30-9 ethyl heptanoate 
• 109-72-8 n-butyllithium 
• 2675-94-7 N,N-diethylacrylamide 
• 693-02-7 hex-1-yne 
• 88-10-8 N,N-diethylcarbamyl chloride 
• 334-19-0 heptanoic acid fluoride 
• 95503-11-0 N,N-Diethyl-2-heptinsaeureamid 
• 111-71-7 heptanal 

Downstream Products

• 2470-68-0 diheptylamine 
• 66793-76-8 ethyl(heptyl)amine 
• 26981-81-7 N,N-diethylheptylamine 

Relevant articles and documents

Radical mediated oxidations in organic chemistry. 3. An efficient and versatile transformation of aldehydes into amides

-

Chemoselective conversion of α-unbranched aldehydes to amides, esters, and carboxylic acids by NHC-catalysis

Depending on the N-heterocyclic carbene catalyst utilized, α-unbranched aldehydes selectively provided amides, esters, or carboxylic acids through oxidation by NCS. The α-unbranched aldehyde underwent these reactions chemoselectively in the presence of an aromatic or α-branched aldehyde.

Reactions of some alkynyl halides with samarium(II) iodide

Certain alkynyl halides (6-halo-1-ynes) react with samarium(II) iodide (SmI2) to give cyclized products (methylenecyclopentanes) in good yield. We have found some interesting evidence for the presence of radical and unstable organosamarium intermediates in these reductive cyclizations. Methyl 7-halohept-2-ynoates are not, however, good substrates for this cyclization methodology.