1038923-52-2Relevant academic research and scientific papers
Nickel-Catalyzed Three-Component Coupling Reaction of Tetrafluoroethylene and Aldehydes with Silanes via Oxa-Nickelacycles
Shirataki, Hiroshi,Ohashi, Masato,Ogoshi, Sensuke
, p. 1883 - 1887 (2019)
The nickel-catalyzed synthesis of a variety of fluorine-containing silyl ethers from tetrafluoroethylene (TFE) and aldehydes with silanes in a selective manner is disclosed. Stoichiometric reactions revealed that the oxa-nickelacycle, which is generated u
Insight into the reactions of trifluorovinylsilanes with aromatic aldehydes
Kirij, Nataliia V.,Dontsova, Dariya A.,Pavlenko, Natalya V.,Yagupolskii, Yurii L.,Scherer, Harald,Tyrra, Wieland,Naumann, Dieter
experimental part, p. 2267 - 2272 (2009/04/05)
The conditions for the selective addition of trialkyl(trifluorovinyl) silanes to the C=O bond of aromatic aldehydes in the presence of cesium fluoride to give the corresponding "silylated" alcohols in high yields was performed. The reactivity of the "sily
