1039136-54-3Relevant academic research and scientific papers
Synthesis of fluorinated allylic amines: Reaction of 2-(trimethylsilyl)ethyl sulfones and sulfoxides with fluorinated imines
Fustero, Santos,Flores, Sonia,Cu?at, Ana C.,Jiménez, Diego,del Pozo, Carlos,Bueno, Jorge,Sanz-Cervera, Juan F.
, p. 1248 - 1254 (2007)
A new synthesis of fluorinated allylamines through the reaction of 2-(trimethylsilyl)ethyl sulfones and sulfoxides (as vinyl anion equivalents) with imines and imino esters has been described. The process includes a TBAF-mediated fragmentation of 2-(trime
Selective formal transesterification of fluorinated 2-(trimethylsilyl)ethyl α-imino esters mediated by TBAF
Fustero, Santos,Sanchez-Rosello, Maria,Rodrigo, Vanessa,Garcia, Amador,Catalan, Silvia,Del Pozo, Carlos
, p. 5617 - 5620 (2008/12/21)
(Chemical Equation Presented) The scope of the transesterification reaction between β-fluorinated α-imino esters and various electrophiles in the presence of TBAF as fluorine source is described. The reaction is highly selective for alkyl iodides, bromide
