104017-23-4

Basic information

• Product Name: 3,4,5-tri-O-tert-butyldimethylsilyl-1,5-anhydro-2-deoxy-D-arabino-hexitol
• CAS NO: 104017-23-4
• Molecular Weight: 490.947
• Mol File: 104017-23-4.mol

Chemical Properties

• CAS DataBase Reference: 3,4,5-tri-O-tert-butyldimethylsilyl-1,5-anhydro-2-deoxy-D-arabino-hexitol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,5-tri-O-tert-butyldimethylsilyl-1,5-anhydro-2-deoxy-D-arabino-hexitol(104017-23-4)
• EPA Substance Registry System: 3,4,5-tri-O-tert-butyldimethylsilyl-1,5-anhydro-2-deoxy-D-arabino-hexitol(104017-23-4)

Safety Data

• Hazardous Substances Data: 104017-23-4(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 515821-31-5 phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-α,β-D-arabino-hexopyranoside 

Relevant articles and documents

Preparation and reductive lithiation of 2-deoxy-D-glucopyranosyl phenylsulfones: A highly stereoselective route to C-glycosides

2-Deoxy-D-glucopyranosyl phenylsulfones 3a-c have been synthesized in 75-83% yield from commercial tri-O-acetyl-D-glucal 1. Their reductive desulfonylation by lithium naphthalenide and reaction of the intermediate glycosyl-lithium 5 with aldehydes leads t