Preparation and reductive lithiation of 2-deoxy-D-glucopyranosyl phenylsulfones: A highly stereoselective route to C-glycosides

DOI: 10.1016/S0040-4039(00)95048-2

Source and publish data:

Tetrahedron Letters p. 6185 - 6188 (1985)

Update date:2022-09-26

Topics:

Authors:

Beau Beau

Sinay Sinay

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95048-2

2-Deoxy-D-glucopyranosyl phenylsulfones 3a-c have been synthesized in 75-83% yield from commercial tri-O-acetyl-D-glucal 1. Their reductive desulfonylation by lithium naphthalenide and reaction of the intermediate glycosyl-lithium 5 with aldehydes leads t

Full text of DOI:10.1016/S0040-4039(00)95048-2

Products guided by the article

Product name:3,4,5-tri-O-tert-butyldimethylsilyl-1,5-anhydro-2-deoxy-D-arabino-hexitol

Cas No:104017-23-4

R&D Labs maybe for 104017-23-4

Xian Changyue Biological Technology Co., Ltd.

website:https://www.xachangyue.com/

Contact:+86-029-88211911

Address:Keji Road NO.70
HOST COUNTRY LIMITED

Contact:+852 83038667

Address:Room 1502, 15th Floor, SPA Centre,53-55 Lockhart Road, Wanchai, Hong Kong
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City

Relevant to this article

Bifunctional copper-based photocatalyst for reductive pinacol-type couplings

Doi:10.1021/acscatal.9b01718
(2019)
Regio- and stereoselectivity control in palladium-catalyzed allylic alkylation of 1-cycloalkenylmethyl acetates

Doi:10.1016/j.tet.2008.04.059
(2008)
Solution phase measurement of both weak σ and C-H...X ^- hydrogen bonding interactions in synthetic anion receptors

Doi:10.1021/ja8035652
(2008)
Diarylmethyloxime and hydrazone derivatives with 5-indolyl moieties as potent inhibitors of tubulin polymerization

Doi:10.1016/j.bmc.2008.04.054
(2008)
Energy- and charge-transfer processes in a perylene-BODIPY-pyridine tripartite array

Doi:10.1002/ejoc.200800159
(2008)
An Efficient Synthesis of α-Iodo Derivatives of Sulfones, Sulfoximines, and Phosphine Oxides

Doi:10.1055/s-1985-31415
(1985)

Article Doi