Preparation and reductive lithiation of 2-deoxy-D-glucopyranosyl phenylsulfones: A highly stereoselective route to C-glycosides

DOI: 10.1016/S0040-4039(00)95048-2

Source and publish data:

Tetrahedron Letters p. 6185 - 6188 (1985)

Update date:2022-09-26

Topics:

Authors:

Beau Beau

Sinay Sinay

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Article abstract of DOI:10.1016/S0040-4039(00)95048-2

2-Deoxy-D-glucopyranosyl phenylsulfones 3a-c have been synthesized in 75-83% yield from commercial tri-O-acetyl-D-glucal 1. Their reductive desulfonylation by lithium naphthalenide and reaction of the intermediate glycosyl-lithium 5 with aldehydes leads t

Full text of DOI:10.1016/S0040-4039(00)95048-2

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