10405-52-4Relevant articles and documents
Tetrathiomolybdate mediated rearrangement of aziridinemethanol tosylates: A thia-aza-payne rearrangement
Sureshkumar, Devarajulu,Koutha, Srinivasamurthy,Ganesh, Venkataraman,Chandrasekaran, Srinivasan
experimental part, p. 5533 - 5541 (2010/11/04)
Aziridinemethanol sulfonate esters react with tetrathiomolybdate 1 to give thiirane derivatives as the major product and cyclic disulfides as minor product under mild reaction conditions via an unprecedented thia-aza-Payne-type rearrangement. Interestingly, when the reaction of 1 was carried out with 2-aziridino-cyclohexanol derivatives it resulted in the formation of thia-bicyclo[3.1.1]heptane or dithia-bicyclo[3.2.1]octane derivatives.