10405-84-2 Usage
Uses
cis-4-Nonene is used in preparation of Immobilized metal Alkylidene Imidazolidene Carbene Alkoxide catalysts and use thereof in olefin metathesis.
Health Hazard
Recommended Personal Protective Equipment: Respiratory organic vapor canister or air-supplied mask; face splash shield; Symptoms Following Exposure: High vapor concentrations irritate eyes and respiratory tract and act as an anesthetic; General Treatment for Exposure: INHALATION: remove patient to fresh air; if breathing stops, apply artificial respiration and administer oxygen; call a physician. INGESTION: do NOT induce vomiting because of aspiration hazard; Toxicity by Inhalation (Threshold Limit Value): Data not available; Short-Term Inhalation Limits: Data not available; Toxicity by Ingestion: Data not available; Late Toxicity: Data not available; Vapor (Gas) Irritant Characteristics: Vapors cause a slight smarting of the eyes or respiratory system if present at high concentrations. The effect is temporary; Liquid or Solid Irritant Characteristics: Minimum hazard. If spilled on clothing and allowed to remain, may cause smarting and reddening of the skin; Odor Threshold: Data not available.
Chemical Reactivity
Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Check Digit Verification of cas no
The CAS Registry Mumber 10405-84-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,4,0 and 5 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 10405-84:
(7*1)+(6*0)+(5*4)+(4*0)+(3*5)+(2*8)+(1*4)=62
62 % 10 = 2
So 10405-84-2 is a valid CAS Registry Number.
InChI:InChI=1/C9H18/c1-3-5-7-9-8-6-4-2/h7,9H,3-6,8H2,1-2H3/b9-7-
10405-84-2Relevant articles and documents
Hydroboration. 86. Convenient Conversion of Aldehydes and Ketones into the Corresponding Alkenes via Hydroboration of their Enamines. A Remarkably Simple Synthesis of Either (Z)- or (E)-Alkenes
Singaram, Bakthan,Rangaishenvi, Milind V.,Brown, Herbert C.,Goralski, Christian G.,Hasha, Dennis L.
, p. 1543 - 1549 (2007/10/02)
Aldehydes and ketones are converted into the corresponding alkenes via hydroboration of their enamines.Hydroboration of aldehyde enamines by 9-borabicyclononane (9-BBN), followed by methanolysis, affords the corresponding terminal alkenes in 75-90percent yields.Unsaturated aldehyde enamines produce the corresponding dienes under these conditions.Enamines derived from substituted cyclic ketones and heterocyclic ketones are readily accommodated in this reaction to afford the corresponding alkenes in very good yields.The synthesis of pure (Z)- or (E)-alkenes is readily achieved from the same acyclic ketone enamine by modification of the hydroboration-elimination procedure: (A) hydroboration by 9-BBN followed by methanolysis or (B) hydroboration by borane methyl sulfide (BMS) followed by methanolysis and hydrogen peroxide oxidation.Mechanistic rationale is provided.
Molybdenum Metalloazines. New Reagents for C=C Bond Formation by an Organometallic Analogue of the "Wittig" Reaction
Smegal, John A.,Meier, Ingrid K.,Schwartz, Jeffrey
, p. 1322 - 1323 (2007/10/02)
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Debromination of vic-Dibromides with Zinc and a Catalytic Amount of Titanium(IV) Chloride in Tetrahydrofuran
Sato, Fumie,Akiyama, Toshio,Iida, Katsumi,Sato, Masao
, p. 1025 - 1026 (2007/10/02)
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