1040735-69-0

Upstream product

• 186581-53-3 diazomethane 
• 504-02-9 1,3-cylohexanedione 
• 926-57-8 1,3-dichloro-2-butene 
• 51577-39-0 3-(6-oxo-cyclohexen-1-enyl)propionic acid methyl ester 
• 1040735-67-8 ethyl 5,9-dioxodecanoate 
• 1106986-12-2 C₁₀H₁₃BrO₃ 
• 917-54-4 methyllithium 
• 67-56-1 methanol 

Downstream Products

• 1040735-71-4 (3R,7aS,11aS)-8-methyl-5-oxo-3-phenyl-2,3,5,6,7,7a,10,11-octahydrooxazolo[2,3-j]quinoline 
• 1040735-89-4 (3R,7aR,11aR)-8-methyl-5-oxo-3-phenyl-2,3,5,6,7,7a,10,11-octahydrooxazolo[2,3-j]quinoline 
• 380605-67-4 5-(2-methyl-6-oxo-cyclohexyl)-pent-2-ynoic acid methyl ester 
• 323577-60-2 3-(2-methyl-6-oxo-cyclohexyl)-propionaldehyde 

Relevant academic research and scientific papers

Biomimetic construction of the hydroquinoline ring system. Diastereodivergent enantioselective synthesis of 2,5-disubstituted cis -decahydroquinolines

Figure presented The straightforward enantioselective construction of the hydroquinoline ring system from 1,5-polycarbonyl derivatives, using (R)-phenyglycinol as a chiral latent form of ammonia, is reported. The process mimics the key steps believed to o

A biomimetic enantioselective approach to the decahydroquinoline class of dendrobatid alkaloids

(Chemical Equation Presented) A princely synthesis: The hypothetical key step in the biosynthesis of the decahydroquinoline dendrobatid alkaloids, such as cis-195 A found in frogs, from 1,5-polycarbonyl derivatives is mimicked by using (R)-phenylglycinol as a chiral latent form of ammonia in a double cyclocondensation reaction.

1,5-Hydrogen atom transfer/radical cyclization of cycloalkanones bearing a β-iodo α,β-unsaturated ester or nitrile side chain

Treatment of cycloalkanones, each bearing β-iodo α,β-unsaturated ester or nitrile side chains, with tributyltin hydride and AIBN effected a 1,5-hydrogen atom transfer/radical cyclization sequence to afford the fused- or spiro-cyclic ketones. (C) 2000 Else