104079-27-8

Upstream product

• 78490-09-2 1-benzoyl-1-<2-(hydroxy)phenoxy>ethane 
• 120-80-9 benzene-1,2-diol 
• 2114-00-3 2-bromo-1-phenyl-1-propanone 
• 14212-54-5 (+)-(R,R)-β-methylstyrene oxide 

Downstream Products

• 104079-29-0 Acetic acid (1R,2S)-2-(2-acetoxy-phenoxy)-1-phenyl-propyl ester 
• 78490-10-5 cis-2-methyl-3-phenyl-1,4-benzodioxan 
• 104153-46-0 (+)-(2S,3S)-3-methyl-2-phenyl-1,4-benzodioxane 
• 104153-47-1 (-)-(2R,3S)-3-methyl-2-phenyl-1,4-benzodioxane 
• 78490-10-5 trans-2-methyl-1,4-bemzodioxan 

Relevant academic research and scientific papers

THE INFLUENCE OF α-ARYL ETHERS ON THE ASYMMETRIC REDUCTION OF CARBONYLS

The asymmetric reduction of α-aryl ethers 1 was found to be strongly influenced by the presence of ortho substituents on the aryl ring.Groups (methoxy or hydroxy) that chelate metal cations tend to stabilize a "locked" bicyclic 4 which, intermediate when

Asymmetric Synthesis of 3-methyl-2-phenyl-1,4-benzodioxanes. Absolute Configuration of the Neolignans Eusiderin and Eusiderin C and D

The asymmetric synthesis of 2S,3S- and 2R,3S-3-methyl-2-phenyl-1,4-benzodioxane from (-)-ephedrine is reported.Comparison of the c.d. curves of these compounds with those of the natural neolignans eusiderin and eusiderin C allows the assignment of 2R,3R configuration to eusiderin and of 2R,3S configuration to eusiderin C and eusiderin D.

Stereospecific Synthesis of 2,3-Disubstituted 1,4-Benzodioxans

The synthesis of cis- and trans-2-methyl-3-phenyl-1,4-benzodioxans 4 and 5, from 1-phenyl-2-propanols threo 2 and erythro 3 are described.