104178-99-6

Basic information

• Product Name: 6-Methoxy-2-methyl-benzyldimethylamin; 3-Methoxy-2-dimethylaminomethyl-toluol
• CAS NO: 104178-99-6
• Molecular Weight: 179.262
• Mol File: 104178-99-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-Methoxy-2-methyl-benzyldimethylamin; 3-Methoxy-2-dimethylaminomethyl-toluol(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Methoxy-2-methyl-benzyldimethylamin; 3-Methoxy-2-dimethylaminomethyl-toluol(104178-99-6)
• EPA Substance Registry System: 6-Methoxy-2-methyl-benzyldimethylamin; 3-Methoxy-2-dimethylaminomethyl-toluol(104178-99-6)

Safety Data

• Hazardous Substances Data: 104178-99-6(Hazardous Substances Data)

Upstream product

• 50868-73-0 2-methoxy-6-methylbenzeneamine 
• 5345-42-6 1-methoxy-3-methyl-2-nitro-benzene 
• 126062-59-7 (3-Methoxy-benzyl)-dimethyl-trimethylsilanylmethyl-ammonium; bromide 
• 50339-64-5 (isobutoxymethyl)dimethylamine 
• 38197-43-2 2-bromo-3-methylanisole 
• 108-39-4 3-methyl-phenol 
• 4920-77-8 3-methyl-2-nitrophenol 

Downstream Products

• 6161-65-5 2-methoxy-6-methyl-benzoic acid 

Relevant articles and documents

Intermediate in Sommelet-Hauser Rearrangement of N,N-Dimethylbenzylammonium N-Methylides

Formation of benzylammonium N-methylides by fluoride anion induced desilylation of dimethyl(4-substituted benzyl)ammonium halides (1) and 3-substituted benzyl analogues (6) was examined to isolate 5--6-methylene-1,3-cyclohexadienes (isotoluene intermediates, 3,8,10) in the Sommelet-Hauser rearrangement.Some isotoluenes were isolated and their structures were confirmed by 1H NMR analysis.The stability of the isotoluenes was dependent on the electron-donating effects of the substituents on the conjugated bonds, and 3-methoxy-substituted isotoluene 3a was the most stable compound studied.