104395-39-3

Usage

Uses

Used in Pesticide Industry:
2,2,2-Trifluoro-1-(4-methoxyphenyl)ethyl Bromide is used as an active ingredient in pesticidal compositions for its ability to control and manage pests effectively. Its chemical structure allows it to interfere with the normal physiological processes of pests, leading to their death or reduced reproduction rates. 2,2,2-Trifluoro-1-(4-methoxyphenyl)ethyl Bromide is particularly useful in the development of new pesticides with improved efficacy and selectivity, targeting specific pests while minimizing harm to non-target organisms and the environment.

Upstream product

• 104395-38-2 Methanesulfonic acid 2,2,2-trifluoro-1-(4-methoxy-phenyl)-ethyl ester 
• 17556-42-2 2,2,2-trifluoro-1-(4-methoxyphenyl)ethanol 
• 371-67-5 2,2,2-trifluorodiazoethane 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 17556-42-2 2,2,2-trifluoro-1-(4-methoxyphenyl)ethanol 
• 150935-07-2 1-(4-Methoxyphenyl)-2,2,2-trifluoroethyl azide 
• 157928-44-4 1-methoxy-4-(2,2,2-trifluoroethyl)benzene 
• 384-97-4 4,4'-(2,2,2-trifluoroethane-1,1-diyl)bis(methoxybenzene) 
• 122425-21-2 N-(Methoxyethyl)-1-(4-methoxyphenyl)-2,2,2-trifluoroethylamine 
• 122425-20-1 N-(Methoxyethyl)-1-(4-((methoxyethyl)amino)phenyl)-2,2,2-trifluoroethylamine 
• 122425-18-7 N,N-Dimethyl-1-(4-methoxyphenyl)-2,2,2-trifluoroethylamine 
• 122425-19-8 N,N-Dimethyl-1-((4-dimethylamino)phenyl)-2,2,2-trifluoroethylamine 
• 122425-23-4 [4-(1-Dimethylamino-2,2,2-trifluoro-ethyl)-phenyl]-(2-methoxy-ethyl)-amine 
• 122425-24-5 Dimethyl-{4-[2,2,2-trifluoro-1-(2-methoxy-ethylamino)-ethyl]-phenyl}-amine 

Relevant academic research and scientific papers

Photoredox-Catalyzed Ring-Opening Addition Reaction between Benzyl Bromides and Cyclic Ethers

A novel nucleophilic reaction between cyclic ethers and benzyl bromides is achieved under photoredox catalysis. The reaction proceeds through a single-electron-transfer (SET) pathway rather than a common SN2 mechanism. By two steps of reduction and oxidation, a benzyl bromide heterolyzes to give a carbocation and bromide ion under mild conditions, and then a cyclic ether captures both the carbocation and bromide ion to afford the addition product.

Generation of Carbocations under Photoredox Catalysis: Electrophilic Aromatic Substitution with 1-Fluoroalkylbenzyl Bromides

A novel Friedel-Crafts-type alkylation of arenes to access valuable 1-fluoroalkyl-1,1-biaryl compounds is established under mild conditions. The key to success is the efficient generation of a destabilized benzylic carbocation intermediate via two consecutive single-electron transfer processes by virtue of visible-light photoredox catalysis. This unique activation pattern avoids using strong Lewis acids and high temperatures that are required for generation of destabilized carbocations in traditional Friedel-Crafts reactions. This protocol demonstrates the first example of photoredox-catalyzed heterolysis of electronically deactivated benzylic C-Br bonds for the formation of destabilized carbocation intermediates.

Synthesis of Chiral α-CF3-Substituted Benzhydryls via Cross-Coupling Reaction of Aryltitanates

We describe a highly efficient approach toward α-CF3-substituted benzhydryls thanks to the employment of organotitanium(IV) based nucleophiles. The use of commercially available anesthetic halothane as a cheap fluorinated building block in a sequential one-pot nickel-catalyzed enantioselective cross-coupling reaction of aryl titanates allowed for the synthesis of chiral α-CF3-substituted benzhydryls in good yields and excellent enantioselectivities. Alternatively, α-CF3-benzyl bromides could be employed under similar conditions to obtain the same family of compounds in higher yields and excellent selectivities. A benzhydryl moiety is a common motif in many biologically active compounds, and their enantioenriched fluorinated analogs should be of great interest in the search for novel drugs and agrochemicals.

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes associated therewith.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula (“Formula One”).

SYNTHESIS AND USE OF FLUORINATED COMPOUNDS

The invention is directed to the preparation of fluorinated compounds and their use in organic synthesis. In particular, the invention is directed to methods of reacting compounds of structure with Rf-CH=N2 or (CF3)2C=N2 to form a perfluoroalkylate or -arylated compounds, and products derived from these reactions, where X, YB, and Rf are described herein.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula ("Formula One"): and processes associated therewith.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): and processes associated therewith.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): and processes associated therewith.

Synthesis and applications of α-trifluoromethylated alkylboron compounds

RBF3K is a chemist's BFF: A metal-free synthetic route to unprecedented organoboron compounds bearing an α-trifluoromethyl substituent, employing a variety of trifluoroborate (RBF3K) starting materials, is reported. These substrates represent the first isolated α-trifluoromethylated alkylboron building blocks, and these reagents lead to a variety of useful bench-stable, synthetic intermediates. Pin=pinacol. Copyright