104412-66-0Relevant academic research and scientific papers
SYNTHESIS OF ARYL- AND HETARYLPHOSPHONATES
Demnik, N. N.,Kabachnik, M. M.,Novikova, Z. S.,Beletskaya, I. P.
, p. 1913 - 1915 (1992)
The reaction of tris(trimethylsilyl) phosphite with aryl or hetaryl halides under homogeneous catalysis conditions gave bis(trimethylsilyl)phosphonates.Treatment of these products with methanol gave the corresponding aryl- or hetarylphosphonic acids in quantitative yield.Keywords: tris(trimethylsilyl) phosphite, aryl and hetaryl halides, homogeneous catalysis, bis(trimethylsilyl)phosphonates, arylphosphonic acids.
PREPARATION OF ARYLPHOSPHONATES BY THE REACTION OF ARYL HALIDES WITH TRIS(TRIMETHYLSILYL) PHOSPHITE UNDER HOMOGENEOUS CATALYSIS CONDITIONS
Demik, N. N.,Kabachnik, M. M.,Novikova, Z. S.,Beletskaya, I. P.
, p. 1300 - 1301 (2007/10/02)
The reaction of tris(trimethylsilyl) phosphite with aryl bromides under homogeneous catalysis conditions gives bis(trimethylsilyl)arylphosphonates.The desilylation of these phosphonate products with methanol leads to arylphosphonic acids.
