Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1913 - 1915 (1992)
Update date:2022-09-26
Topics: Michaelis-Arbuzov reaction Cross-Coupling Reactions Hirao Reaction Sonogashira Reaction
Demnik, N. N.
Kabachnik, M. M.
Novikova, Z. S.
Beletskaya, I. P.
The reaction of tris(trimethylsilyl) phosphite with aryl or hetaryl halides under homogeneous catalysis conditions gave bis(trimethylsilyl)phosphonates.Treatment of these products with methanol gave the corresponding aryl- or hetarylphosphonic acids in quantitative yield.Keywords: tris(trimethylsilyl) phosphite, aryl and hetaryl halides, homogeneous catalysis, bis(trimethylsilyl)phosphonates, arylphosphonic acids.
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