1044591-69-6Relevant academic research and scientific papers
MgI2 etherate-catalyzed three-component allylation: A facile and efficient synthesis of homoallylic amines
Zhang, Xingxian,Ye, Saisai,Hu, Shenghui
, p. 427 - 430 (2011)
MgI2 etherate-catalyzed three-component condensation of aldehydes, amines and allyltributylstannane under mild and neutral reaction conditions was developed and efficiently afforded the corresponding homoallylic amine derivatives in good to exc
Catalyst-free allylation of 2-aminophenol–derived aldimines with allyltrichlorosilane under thermal conditions
Venkatanna, Kesa,Ramanathan, Chinnasamy Ramaraj
, p. 3650 - 3653 (2017/08/22)
Allylation of 2-aminophenol-derived aldimines using allyltrichlorosilane under catalyst free conditions has been developed. This reaction afforded the corresponding homoallylic amines in good to excellent yields (68–94%). The salicylaldehyde-derived aldimines as well as benzoylhydrazone also found to react with allyltrichlorosilane smoothly under the same conditions, to furnish the corresponding homoallylic amine derivatives. This study suggests that the phenolic –OH group acts as an anchoring group for the transfer of allyl group from allyl silane reagent.
Highly efficient synthesis of homoallylamines from aldimines with allylstannane promoted by MgI2 etherate
Zhang, Xingxian,Hu, Shenghui,Shi, Junchen
experimental part, p. 336 - 339 (2010/11/03)
We describe a mild and efficient procedure for the synthesis of homoallylamines by addition of allyltributylstannane to aldimines with promoted by MgI2 etherate (MgI2?(OEt2)n) in good to excellent yields.
