1044844-34-9Relevant academic research and scientific papers
A chemoselective aerobic oxidation of benzylic azides catalyzed by molybdenum xanthate in an aqueous medium
Maddani, Mahagundappa,Prabhu, Kandikere Ramaiah
, p. 4526 - 4530 (2008)
A mild molybdenum-catalyzed, aerobic, chemoselective oxidation of benzylic azides to the corresponding aldehydes in an aqueous medium that tolerates a variety of functional groups including alcohols, esters, ketones, halides and olefins is described.
An efficient oxidation of primary azides catalyzed by copper iodide: A convenient method for the synthesis of nitriles
Lamani, Manjunath,Prabhu, Kandikere Ramaiah
supporting information; experimental part, p. 6622 - 6625 (2010/11/04)
A wide range of primary azides have been efficiently oxidized by a catalytic amount of CuI and TBHP into their corresponding nitriles in aqueous solution. A variety of oxidizable functional groups were well tolerated under the reaction conditions, and oxidation of secondary azides furnished their corresponding ketones (see scheme; TBHP=tert-butyl hydroperoxide).
