104486-05-7

Basic information

• Product Name: MCPMB
• Synonyms: MCPMB;methyl 2-(4-chlorophenyl)-3-methylbutyrate;Methyl 2-(4-chlorophenyl)-3-Methylbutanoate
• CAS NO: 104486-05-7
• Molecular Formula: C12H15 Cl O2
• Molecular Weight: 226.7
• Mol File: 104486-05-7.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 280.9°Cat760mmHg
• Flash Point: 127.9°C
• Appearance: /
• Density: 1.106g/cm³
• Vapor Pressure: 0.00367mmHg at 25°C
• Refractive Index: 1.507
• CAS DataBase Reference: MCPMB(CAS DataBase Reference)
• NIST Chemistry Reference: MCPMB(104486-05-7)
• EPA Substance Registry System: MCPMB(104486-05-7)

Safety Data

• Hazardous Substances Data: 104486-05-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H15ClO2/c1-8(2)11(12(14)15-3)9-4-6-10(13)7-5-9/h4-8,11H,1-3H3

Upstream product

• 75-30-9 2-iodo-propane 
• 52449-43-1 (4-chloro-phenyl)-acetic acid methyl ester 
• 67-56-1 methanol 
• 2012-74-0 2-(4-chlorophenyl)-3-methylbutyric acid 
• 86618-06-6 methyl 2-(4-chlorophenyl)-3-methylbutanoate 
• 924-50-5 Methyl 3,3-dimethylacrylate 
• 106-39-8 bromochlorobenzene 
• 140-53-4 p-chlorobenzyl cyanide 
• 956498-38-7 α-cyano-3-phenoxybenzyl S-(+)-2-(4-chlorophenyl)isovalerate 

Relevant articles and documents

Synthesis and Applications of Unquaternized C-Bound Boron Enolates

A general and facile method to prepare unquaternized C-bound boron enolates by a ligand-controlled O-to-C isomerization is reported. Using this protocol, C-bound pinacolboron enolates have been isolated in pure form for the first time, and have been fully characterized by NMR spectroscopy and X-ray crystallography. In contrast to the general perception, such C-boron enolates are stable without coordinative saturation at the boron. Moreover, C-boron enolates present reactivities that are distinct from the O-boron enolates, and their applications in C-O and C-C bond formations are demonstrated.

Process for preparing (S)- alpha-cyano-3-phenoxybenzyl-(S)-2-(4-chlorophenyl)-isovalerate

The present invention relates to an environmentally benign process for the preparation of (S)-α-cyano-3-phenoxybenzyl-(S)-2-(4-chlorophenyl)isovalerate from its diastereomeric mixture (RS)-α-cyano-3-phenoxybenzyl-(S)-2-(4-chlorophenyl) isovalerate.

A Novel Electrogenerated Base. Alkylation of Methyl Arylacetates at the α-Methylene Group

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