104527-46-0Relevant articles and documents
The Stereoselective total synthesis of (1S,1'R,5'R,7'R)-1-hydroxy-exo- Brevicomin by a Chiron Approach
Yadav, Jhillu S.,Rao, Kodepelly Sanjeeva,Reddy, Basi V. Subba
, p. 4 - 7 (2009)
(1S,1'R,5'R,7'R)-1-Hydroxy-exo-brevicomin has been synthesized in a highly efficient manner using Dglucono- δ-lactone as a chiral precursor. The synthesis involves the Grignard cross coupling, Wacker oxidation and intramolecular acetalization as the key s
Mannich Reactions of Carbohydrate Derivatives with Ketones to Afford Polyoxy-Functionalized Piperidines
Maram, Lingaiah,Tanaka, Fujie
, p. 1165 - 1169 (2019)
Mannich reactions of carbohydrate derivatives with ketones that afford polyoxy-functionalized piperidines are reported. Ketone nucleophiles (enamines/enolates) were generated in the presence of the amines used for the formation of the iminium ions of suga
Total Synthesis of Microsclerodermin E
Zhu, Jidong,Ma, Dawei
, p. 5348 - 5351 (2007/10/03)
Succumbing to total synthesis: Microsclerodermin E, a 23-membered cyclic hexapeptide possessing antifungal activity, has been prepared for the first time. Key features in the synthesis include the construction of four unusual amino acid units, the assembl