104667-72-3

Basic information

• Product Name: Benzenesulfonamide, N-(5-amino-1H-1,2,4-triazol-3-yl)- (9CI)
• Synonyms: Benzenesulfonamide, N-(5-amino-1H-1,2,4-triazol-3-yl)- (9CI)
• CAS NO: 104667-72-3
• Molecular Formula: C₈H₉N₅O₂S
• Molecular Weight: 239.25436
• Product Categories: SULFONAMIDE
• Mol File: 104667-72-3.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzenesulfonamide, N-(5-amino-1H-1,2,4-triazol-3-yl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-(5-amino-1H-1,2,4-triazol-3-yl)- (9CI)(104667-72-3)
• EPA Substance Registry System: Benzenesulfonamide, N-(5-amino-1H-1,2,4-triazol-3-yl)- (9CI)(104667-72-3)

Safety Data

• Hazardous Substances Data: 104667-72-3(Hazardous Substances Data)

Upstream product

• 104692-80-0 methyl N'-cyano-N-(phenylsulfonyl)imidothiocarbamate 
• 98-10-2 benzenesulfonamide 
• 433223-59-7 C₁₄H₂₁N₅O₄S₂ 
• 98-09-9 benzenesulfonyl chloride 
• 86147-15-1 1-acetyl-3,5-diamino-1H-1,2,4-triazole 
• 104692-80-0 C₉H₉N₃O₂S₂ 
• 2582-30-1 aminoguanidine bicarbonate 
• 13068-20-7 N-bis-(methylsulfanylmethylene)benzenesulfonamide 

Relevant articles and documents

Regioselective single-reactor synthesis of arylsulfonyl derivatives of 3,5-diamino-1,2,4-triazole

Arylsulfonylation of 1-acetyl-3,5-diamino-1,2,4-triazole with arylsulfonyl chlorides in pyridine, with the subsequent hydrolysis of the acetyl group, was studied; a new regioselective method for synthesis of N-(5-amino-1H-1,2,4- triazol-3-yl)arylsulfonami

A novel and efficient regiospecific preparation of arenesulfonamide derivatives of 3,5-diamino-1,2,4-triazole

A new simple and efficient procedure was designed for the regiospecific preparation of arenesulfonamide derivatives of 3,5-diamino-1,2,4-triazole 1 which are precursors of N-([1,2,4] triazolo [1,5-a]pyrimidin-2-yl)arenesulfonamides 2, an important family of herbicidal and antibacterial agents. The key feature of this procedure is the preparation of a wide range of compounds 1 on a large scale, in pure form and high yield without the need for any workup or the use of the highly hazardous hydrazine. This was made possible by a novel tandem reaction promoted by sulfuryl chloride to effect the formation of the triazole ring.

Regiospecific synthesis of N-sulfonyl derivatives of 3,5-diamino-1H-1,2,4-triazole and 2,5-diamino-1,3,4-thiadiazole

Condensation of the S,S-dimethyl N-(alkylsulfonyl)carbondithioimidates 1 with aminoguanidine bicarbonate and hydrazinecarbothioamide leads to the regiospecific synthesis of N-sulfonyl derivatives of 3,5-diamino-1H-1,2,4-triazole 2 and 2,5-diamino-1,3,4-thiadiazole 3, respectively.