104669-26-3

Upstream product

• 83-38-5 2,6-dichlorobenzaldehyde 
• 62-53-3 aniline 
• 15258-73-8 2,6-dichlorobenzyl alcohol 

Downstream Products

• 91283-13-5 1-phenyl-5-(2,6-dichlorophenyl)-1,2,3-triazoline 
• 55516-89-7 chlorotris(trimethylphosphane)cobalt(I) 
• 1007565-13-0 (C₆H₃ClCHNC₆H₅)CoCl(CH₃)(P(CH₃)3)2 
• 1007565-18-5 (C₆H₃ClCHNC₆H₅)CoCl(P(CH₃)3)2 
• 1065565-79-8 C₂₁H₂₅Cl₂N 
• 1137001-17-2 FeCl(P(CH₃)3)3(C₆H₃ClCHNC₆H₅) 
• 83-38-5 2,6-dichlorobenzaldehyde 

Relevant academic research and scientific papers

Selective amination of aryl chlorides catalysed by Ni(PMe3)4

C,N-coupling reactions of aryl chlorides and aryl amines catalyzed by a nickel catalyst are reported. 17 new amines are synthesized in yields of 57-99%. 2,6-Dichloro substituted imines can be selectively aminated. Both mono- and di-aminated products are o

Nano magnetic sulfated zirconia (Fe3O4@ZrO2/SO42-): An efficient solid acid catalyst for the green synthesis of α-aminonitriles and imines

In this research, nano magnetic sulfated zirconia was prepared and characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) measurements and vibrational sample magnetometry (VSM). Its catalytic activity was investigated for the one-pot three component green synthesis of α-aminonitriles using various aldehydes and ketones at room temperature in ethanol. This protocol has various advantages such as: simple work-up, short reaction time, high product yields and easy recovery and reusability of the catalyst.

The Versatility of the Aryne-Imine-Aryne Coupling for the -Synthesis of Acridinium Photocatalysts

The increasing use of acridinium photocatalysts as sustainable alternative to precious metal-based counterparts encourages the design and efficient synthesis of distinct catalyst structures. Herein, we report our exploration of the scope of the aryne-imin

Introduction of (2-CF3)phenyl group via nickel-catalyzed C-CL bond activation and arylation

A simple and mild catalytic arylation via C-Cl bond activation is described. The phenyl group containing a 2-trifluoromethyl group was introduced into the aromatic imine molecules through C,C-coupling reaction between chloroarenes and the organozinc reage

Straightforward synthesis of aromatic imines from alcohols and amines or nitroarenes using an impregnated copper catalyst

The impregnated copper on magnetite catalyst is a versatile system for the synthesis of imines starting from alcohols and amines. This catalyst does not require any type of expensive and difficult to handle organic ligand or typical transition metals, and provides excellent yields achievable under mild reaction conditions. Moreover, the catalyst is very easy to remove from the reaction medium by simply using a magnet. The one-pot process of dehydrogenation of alcohols in the presence of aniline followed by aqueous hydrolysis gave pure alcohols in excellent yields. In addition to amines, nitroarenes could be used as the nitrogen-containing reagent. In the case of primary amines the expected imines were successfully prepared under similar reaction conditions. The impregnated copper on magnetite catalyst is a versatile system for the synthesis of imines starting from alcohols and amines or nitroarenes. A similar synthesis of imines was accomplished using only primary amines. This catalyst avoids the use of expensive organic ligands and other transition metals while enabling excellent yields under mild reaction conditions. Copyright

Microwave assisted solvent free synthesis of azomethines from aryl aldehydes on melamin formaldehyde as solid support

Various aryl aldehydes underwent prompt one pot conversion into the corresponding azomethines in high yields by reacting with hydroxylamine hydrochloride supported on melamine formaldehyde under microwave irradiation.

Synthetic and mechanistic studies of indium-mediated allylation of imines in ionic liquids

(Chemical Equation Presented) Aldimines derived from aryl and non-enolizable aliphatic aldehydes were allylated with allyl bromide mediated by indium powder in [bpy][BF4] (bpy = N-butylpyridine) to give good yields of the corresponding homoallylic amines. Selective formation of monoallylated amines can be achieved by varying the amount of bromide ion additive in the form of [bpy][Br]. The transient organoindium intermediates, allylindium-(I) and allylindium(III) dibromide formed in the reaction, were studied by NMR spectroscopy to explain the selectivity.