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10468-17-4

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10468-17-4 Usage

General Description

N-(3-chloro-phenyl)hydroxylamine is a chemical compound with the formula C6H6ClNO. It is a white to pale yellow solid with a molecular weight of 143.57 g/mol. N-(3-CHLORO-PHENYL)HYDROXYLAMINE is widely used as a reagent in organic chemistry, particularly in the synthesis of pharmaceuticals and agrochemicals. N-(3-chloro-phenyl)hydroxylamine is known for its ability to react with various functional groups, such as ketones, aldehydes, and imines, to form oximes and hydrazones. It is also used as a precursor in the synthesis of various organic compounds and as a reducing agent in certain reactions. However, it should be handled with caution due to its potential for causing skin and eye irritation, as well as being harmful if ingested or inhaled.

Check Digit Verification of cas no

The CAS Registry Mumber 10468-17-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,4,6 and 8 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 10468-17:
(7*1)+(6*0)+(5*4)+(4*6)+(3*8)+(2*1)+(1*7)=84
84 % 10 = 4
So 10468-17-4 is a valid CAS Registry Number.

10468-17-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name N-(3-chlorophenyl)hydroxylamine

1.2 Other means of identification

Product number -
Other names Benzenamine, 3-chloro-N-hydroxy-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10468-17-4 SDS

10468-17-4Relevant articles and documents

Ultrasound-promoted highly chemoselective reduction of aromatic nitro compounds to the corresponding N-arylhydroxylamines using zinc and HCOONH 4 in CH3CN

Shi, Qi Xun,Lu, Rong Wen,Jin, Kun,Zhang, Zhu Xia,Zhao, De Feng

, p. 226 - 227 (2006)

N-Arylhydroxylamines were prepared in high yields through chemoselective reduction of the corresponding aromatic nitro compounds under ultrasound (59 kHz) at room temperature using a convenient Zn/HCOONH4/CH 3CN system. This method was highly efficient, environmentally benign, especially simple and practical. Copyright

Selective hydrogenation of nitroaromatics to: N -arylhydroxylamines in a micropacked bed reactor with passivated catalyst

Chen, Jian-Li,Cheng, Peng-Fei,Jiang, Zhi-Jiang,Su, Wei-Ke,Xu, Feng,Yu, Zhi-Qun

, p. 28585 - 28594 (2020/08/25)

In this contribution, a protocol was established for the selective catalytic hydrogenation of nitroarenes to the corresponding N-arylhydroxylamines. The reduction of 1-(4-chlorophenyl)-3-((2-nitrobenzyl)oxy)-1H-pyrazole, an intermediate in the synthesis of the antifungal reagent pyraclostrobin that includes carbon-chlorine bonds, benzyl groups, carbon-carbon double bonds and other structures that are easily reduced, was chosen as the model reaction for catalyst evaluation and condition optimization. Extensive passivant evaluation showed that RANEY-nickel treated with ammonia/DMSO (1 : 10, v/v) afforded the optimal result, especially with a particle size of 400-500 mesh. To combine the modified catalyst with continuous-flow reaction technology, the reaction was conducted at room temperature, rendering the desired product with a conversion rate of 99.4% and a selectivity of 99.8%. The regeneration of catalytic activity was also studied, and an in-column strategy was developed by pumping the passivate liquid overnight. Finally, the generality of the method was explored, and 7 substrates were developed, most of which showed a good conversion rate and selectivity, indicating that the method has a certain degree of generality.

Regioselective installation of fluorosulfate (-OSO2F) functionality into aromatic C(sp2)-H bonds for the construction of: Para-amino-arylfluorosulfates

Fang, Wan-Yin,Zha, Gao-Feng,Zhao, Chuang,Qin, Hua-Li

supporting information, p. 6273 - 6276 (2019/06/07)

The construction of para-amino-arylfluorosulfates was achieved through installation of fluorosulfate (-OSO2F) functionality into aromatic C(sp2)-H bonds by the reaction of N-arylhydroxylamine with sulfuryl fluoride (SO2Fs

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