1046834-55-2Relevant academic research and scientific papers
Aerobic Linear Allylic C-H Amination: Overcoming Benzoquinone Inhibition
Pattillo, Christopher C.,Strambeanu, Iulia I.,Calleja, Pilar,Vermeulen, Nicolaas A.,Mizuno, Tomokazu,White, M. Christina
, p. 1265 - 1272 (2016)
An efficient aerobic linear allylic C-H amination reaction is reported under palladium(II)/bis-sulfoxide/Br?nsted base catalysis. The reaction operates under preparative, operationally simple conditions (1 equiv of olefin, 1 atm O2 or air) with
Palladium-catalyzed allylic C-H amination of alkenes with N-fluorodibenzenesulfonimide: Water plays an important role
Xiong, Tao,Li, Yan,Mao, Lujia,Zhang, Qian
supporting information; experimental part, p. 2246 - 2248 (2012/03/27)
A new palladium-catalyzed highly regioselective allylic C-H amination of alkenes with NFSI in the presence of a catalytic amount of water was developed and successfully expanded to Selectfluor-mediated palladium-catalyzed aminations of alkenes with N-tosy
Scope and mechanism of allylic C-H amination of terminal alkenes by the palladium/PhI(OPiv)2 catalyst system: Insights into the effect of naphthoquinone
Yin, Guoyin,Wu, Yichen,Liu, Guosheng
supporting information; experimental part, p. 11978 - 11987 (2010/11/02)
Palladium-catalyzed oxidative amination of unactivated alkyl olefins has been developed to produce linear (E)-allylimides with high regioselectivity. This highly efficient transformation of alkenes has been achieved by enhancing the reoxidation of palladi
Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: Efficient synthesis of linear allylamine derivatives
Liu, Guosheng,Yin, Guoyin,Wu, Liang
supporting information; body text, p. 4733 - 4736 (2009/02/06)
(Chemical Equation Presented) O2-coupledallylic C-H amination: A first general palladium-mediated intermolecular aerobic oxidative allylic amination was developed to synthesize linear (E)-allylimides with high regioselectivity (see scheme; MA = maleic anhydride). The proposed mechanism involves an allylic C-H activation with subsequent nitrogen nucleophile substitution. The catalytic system allows efficient dioxygen-coupled turnover without additional cocatalysts.
